|
|
| | BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Basic information |
| Product Name: | BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE | | Synonyms: | Bis(diMethylaMino)phosphoryl chloride, 90%, tech.;Bis(diMethylaMino)phosphoryl chloride, tech.;Bis(N,N-diMethylaMino)phosphinic chloride SynonyMs Bis(diMethylaMino)chlorophosphine oxide;N,N,N',N'-Tetramethylphosphorodiamidic chloride technical grade, 90%;Bis(dimethylamino)phosphorylchloride,95+%;bis-(N,N-dimethylamino)-phosphorylchloride;Phosphorodiamidic chloride, N,N,N',N'-tetramethyl-;Phosphorodiamidic chloride, tetramethyl- | | CAS: | 1605-65-8 | | MF: | C4H12ClN2OP | | MW: | 170.58 | | EINECS: | 216-517-1 | | Product Categories: | organophosphorus compound | | Mol File: | 1605-65-8.mol |  |
| | BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Chemical Properties |
| Boiling point | 246-247 °C | | density | 1.152 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.466(lit.) | | Fp | >230 °F | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | solubility | Chloroform (Sparingly), Ethyl Acetate (Slightly) | | pka | -0.04±0.70(Predicted) | | form | Liquid | | color | Colorless | | Specific Gravity | 1.18 | | Sensitive | Moisture Sensitive | | BRN | 471430 | | InChI | InChI=1S/C4H12ClN2OP/c1-6(2)9(5,8)7(3)4/h1-4H3 | | InChIKey | WYLQARGYFXBZMD-UHFFFAOYSA-N | | SMILES | P(N(C)C)(N(C)C)(Cl)=O | | CAS DataBase Reference | 1605-65-8(CAS DataBase Reference) | | EPA Substance Registry System | Phosphorodiamidic chloride, tetramethyl- (1605-65-8) |
| Hazard Codes | C | | Risk Statements | 34-37-20/21/22 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3265 8/PG 2 | | WGK Germany | 3 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29299090 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID | | Uses | N,N,N′,N′-Tetramethylphosphorodiamidic chloride was used in the synthesis of (-)-allohedycaryol and C2-symmetric binaphthyl phosphortriamide. It was also used in total synthesis of neohedycaryol. | | Application | Bis(dimethylamino) Phosphorochloridate is used as a reagent for protection of alcohols, ketones, thiols and amines; reductive deoxygenation of alcohols and
ketones. | | storage | Bis(dimethylamino) Phosphorochloridate is moisture sensitive; store in a dry, cool environment. Handle in a well-ventilated fume hood. |
| | BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Preparation Products And Raw materials |
| Preparation Products | DIMEFOX-->Phosphorodiamidic acid, tetramethyl-, ethyl ester-->Phosphorodiamidic acid, N,N,N',N'-tetramethyl--->CHLORODIMETHYLAMINE-->Hexamethylphosphoramide-->(Phosphoric diethyl)N,N,N',N'-tetramethyldiamidophosphoric anhydride-->Bis(N,N-dimethylamino)-pentachloro-phenyl phosphate |
|