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| | Tetrabutylammonium azide Basic information |
| Product Name: | Tetrabutylammonium azide | | Synonyms: | TETRABUTYLAMMONIUM AZIDE;n,n,n-tributyl-1-butanaminiuazide;N,N,N-Tributyl-1-butanaminium azide;Tetra-n-butylammonium azide, 90+%;Tetrabutylammonium nitride;1-Butanaminium, N,N,N-tributyl-, azide;1-Butanaminium, N,N,N-tributyl-, azide (1:1);Tetrabutylammonium a | | CAS: | 993-22-6 | | MF: | C16H36N4 | | MW: | 284.48 | | EINECS: | | | Product Categories: | Ammonium Polyhalides, etc. (Quaternary);Quaternary Ammonium Compounds;Azidation/Diazo TransferChemical Ligation;Azide Sources;Click Chemistry;C-X Bond Formation (Non-Halogen);Synthetic Reagents | | Mol File: | 993-22-6.mol |  |
| | Tetrabutylammonium azide Chemical Properties |
| Melting point | 84-88 °C (lit.) | | storage temp. | 2-8°C | | Water Solubility | Soluble in water | | form | powder to crystal | | color | White to Light yellow | | Sensitive | Hygroscopic | | InChI | InChI=1S/C16H36N.N3/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-3-2/h5-16H2,1-4H3;/q+1;-1 | | InChIKey | GMRIOAVKKGNMMV-UHFFFAOYSA-N | | SMILES | [N+](CCCC)(CCCC)(CCCC)CCCC.[N+](=[N-])=[N-] | | CAS DataBase Reference | 993-22-6 | | EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, azide (993-22-6) |
| Hazard Codes | T,N | | Risk Statements | 11-50/53-36/37/38-32-25 | | Safety Statements | 15-36/37/39-45-61-60-26 | | RIDADR | 1325 | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29239000 | | Storage Class | 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | | Hazard Classifications | Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Tetrabutylammonium azide Usage And Synthesis |
| Uses | Tetrabutylammonium azide can be used as a reagent for the synthesis of:
- Heteroarylannulated bicyclic morpholines
- Cyanimide-based inhibitors of cathepsin C
- Trimethylene carbonate
- Aerobic oxidative transformation of primary azides to nitriles
- Substitution reactions at tetracoordinate boron
It is also used as a catalyst for cyclic carbonate formation. | | reaction suitability | reaction type: click chemistry |
| | Tetrabutylammonium azide Preparation Products And Raw materials |
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