(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl

(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Suppliers list
Company Name: Career Henan Chemica Co
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Products Intro: Product Name:(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
CAS:1365531-90-3
Purity:98% Package:1g;1.3USD
Company Name: Hangzhou MolCore BioPharmatech Co.,Ltd.
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Products Intro: Product Name:(S)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl
CAS:1365531-90-3
Purity:NLT 98% Remarks:MC519961
Company Name: Shanghai Acmec Biochemical Technology Co., Ltd.
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Products Intro: Product Name:(S)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl
CAS:1365531-90-3
Purity:98% Package:100mg, 1g, 50mg, 250mg
Company Name: Aladdin Scientific
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Products Intro: Product Name:(S)-2,2''-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4'',6,6''-tetramethoxy)-1,1''-biphenyl
CAS:1365531-90-3
Purity:97% Package:$58.9/100mg;$224.9/500mg;Bulk package Remarks:97%
Company Name: SHANGHAI KEAN TECHNOLOGY CO., LTD.
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Products Intro: Product Name:(S)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl
CAS:1365531-90-3
Purity:0.99 Package:100g;1kg;5KG;1KG
(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Basic information
Reaction
Product Name:(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl
Synonyms:(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%;(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, Min. 97% (S)-Xyl-Garphos;(S)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl;(S)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-4,4',6,6'-TETRAMETHOXY)-1,1'-BIPHENYL,MIN.97%(S)-XYL-GARPHOS;(S)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-Xyl-Garphos(TM);(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl (S)-Xyl-Garphos;Phosphine, 1,1'-[(1S)-4,4',6,6'-tetramethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-;(S)-2,2''-Bis[bis(3,5-dimethyL
CAS:1365531-90-3
MF:C48H52O4P2
MW:754.87
EINECS:
Product Categories:Chiral Phosphine;Garphos Series
Mol File:1365531-90-3.mol
(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Structure
(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Chemical Properties
Melting point >300 °C
Boiling point 810.8±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color white
Optical Rotation[α]22/D -87.0, c =0.5% in chloroform
Sensitive Air Sensitive
InChIKeyIDNKFBDRZBLTFQ-UHFFFAOYSA-N
SMILESCOc1cc(OC)c(c(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)-c4c(OC)cc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6
CAS DataBase Reference1365531-90-3
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Usage And Synthesis
ReactionChiral ligand used in the preparation of hydrogenation catalysts with exceptionally high activity and selectivity.
Reactions of 1365531-90-3
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl Preparation Products And Raw materials
Tag:(S)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl(1365531-90-3) Related Product Information
(R)-2,2'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl (S)-2,2'-Bis[bis(4-Methoxy-3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+% (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-2,2'-Bis[bis(3,5-trifluoroMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+% (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%