| Company Name: |
Meryer (Shanghai) Chemical Technology Co., Ltd.
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| Tel: |
4006356688 18621169109 |
| Email: |
market03@meryer.com |
| Products Intro: |
Product Name:(S)-(+)-Acetylcarbonyl((eta)^5-2,4-cyclopentadien-1-yl)(triphenylphosphine)iron
CAS:36548-60-4
Remarks:AAM229872
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| Company Name: |
Chengdu Ai Keda Chemical Technology Co., Ltd.
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| Tel: |
4008-755-333 18080918076 |
| Email: |
800078821@qq.com |
| Products Intro: |
Product Name:(S)-(+)-Acetyl-cyclopentadienyl-iron carbonyl triphenylphosphine coMplex
CAS:36548-60-4
Purity:HPLC;GR;AR;CP Package:5g;25g;100g;500g
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| Company Name: |
Chengdu HuaXia Chemical Reagent Co. Ltd
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| Tel: |
400-1166-196 13458535857 |
| Email: |
cdhxsj@163.com |
| Products Intro: |
Product Name:(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
CAS:36548-60-4
Purity:99% HPLC Package:10g;50g;100g;500g;1kg;5kg;25kg
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| | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Basic information |
| Product Name: | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON | | Synonyms: | IRON ACETYL COMPLEX (-)-(R)-ENANTIOMER;IRON ACETYL COMPLEX (+)-(S)-ENANTIOMER;(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON;(R)-(-)-ACETYLCARBONYL((ETA)5-2,4-CYCLOPENTADIENE-1-YL)(TRIPHENYLPHOSPHINE)IRON;(R)-(-)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;S(+)-CYCLOPENTADIENYL IRON ACETYL CARBONYL TRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLO- PENTANEDIENYL IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX | | CAS: | 36548-60-4 | | MF: | C26H23FeO2P5* | | MW: | 454.28 | | EINECS: | | | Product Categories: | | | Mol File: | 36548-60-4.mol |  |
| | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Chemical Properties |
| Melting point | 151-156 °C | | storage temp. | 2-8°C | | solubility | soluble in THF, CHCl3, CH2Cl2, acetone |
| | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Usage And Synthesis |
| Uses | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON is used as chiral acetate enolate equivalent which can be deprotonated with BuLi or LDA in THF at -78 °C; the enolate reacts stereoselectively with a variety of achiral, prochiral, and chiral electrophiles to generate functionalized organoiron compounds from which the iron can subsequently be removed.
| | storage |
(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON can be stored in air for days with little decomposition. The solid is best stored under nitrogen for long periods of time. More air sensitive when in solution, especially chlorinated hydrocarbons.
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| | (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Preparation Products And Raw materials |
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