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Gymnomitrol

Gymnomitrol Basic information
Product Name:Gymnomitrol
Synonyms:(3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol;Gymnomitrol;4,8-Methanoazulen-9-ol, decahydro-3a,4,8a-trimethyl-7-methylene-, (3aS,4S,8R,8aS,9S)-
CAS:41410-53-1
MF:C15H24O
MW:220.35
EINECS:
Product Categories:
Mol File:41410-53-1.mol
Gymnomitrol Structure
Gymnomitrol Chemical Properties
Boiling point 289.1±9.0 °C(Predicted)
density 1.02±0.1 g/cm3(Predicted)
pka14.72±0.70(Predicted)
Safety Information
MSDS Information
Gymnomitrol Usage And Synthesis
DescriptionGymnomitrol, a novel tricyclic sesquiterpenoid alcohol from the liverwort Gymnomitrion obtusum(Lindb) Pears, is formulated  on chemical and spectroscopic evidence and the novel carbon skeleton is shown to be derivable biogenetically from γ-bisabolene via a trichodiene intermediate.[1]
SynthesisThe tricyclic sesquiterpenoid gymnomitrol was isolated as a major metabolite from liverwort Gymnomitrion obtusum (Lindb.) Pears. The corresponding hydrocarbon, gymnomitrene (previously known as P-barbatene2 or P-pompene3), also occurs with gymnomitrol. The structure and stereochemistry of gymnomitrol were determined by degradation and spectroscopy in conjunction with biogenetic considerations. The unique carbon framework of this cyclotrichothecane is thought to arise, biogenetically, from bazzanene.
Gymnomitrol synthesis
References[1] J. D. CONNOLLY   Ian M S T  A E Harding. Gymnomitrol, a novel tricyclic sesquiterpenoid from Gymnomitrion obtusum(Lindb) Pears (hepaticae)[J]. Journal of The Chemical Society, Chemical Communications, 1972, 42 1: 1320-1321. DOI:10.1039/C39720001320.
Gymnomitrol Preparation Products And Raw materials
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