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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

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Products Intro: Product Name:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS:1375325-71-5
Purity:99% Package:25KG
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Products Intro: Product Name:Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
CAS:1375325-71-5
Purity:98% Package:1g;10g;25g
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Products Intro: Product Name:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS:1375325-71-5
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Products Intro: Product Name:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS:1375325-71-5
Purity:99% Package:1KG,5KG,10KG
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Products Intro: Product Name:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS:1375325-71-5
Purity:99% Package:1KG;7USD

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) manufacturers
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Basic information
Physical Form Reaction
Product Name:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Synonyms:Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2'-amino[1,1'-biphenyl]-2-yl]palladium(II);Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);tBu3PPdG2 catalyst;Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;P(t-Bu)3 Palladacycle Gen.2
CAS:1375325-71-5
MF:C24H37ClNPPd
MW:512.41
EINECS:
Product Categories:Pd
Mol File:1375325-71-5.mol
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Structure
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties
Melting point 158-160°C
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color yellow
InChIInChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
InChIKeyCCFGXRYKSYUWKT-UHFFFAOYSA-N
SMILESP([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C
Safety Information
WGK Germany 3
HS Code 2931.90.6000
Storage Class11 - Combustible Solids
MSDS Information
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Usage And Synthesis
Physical Form Light yellow to Amber to Dark green powder to crystal.
ReactionCatalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates. Reactions of 1375325-71-5
UsesP(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies:
  • Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
  • Stille cross-couplings reactions of aryl chloride.
  • Synthesis of chloropeptin I, via Stille cross-coupling reaction.
  • Heck reaction.
  • Negishi cross-coupling reactions.
ApplicationCatalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.
General DescriptionP(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials
Tag:Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)(1375325-71-5) Related Product Information
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) tBuXPhos-Pd-G3 cataCXium A-Pd-G2 Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct P(t-Bu)3 Pd G4 Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) XPhos Pd G2 SPhos Pd G2 RuPhos Pd G2 Chloro[tri(p-tolyl)phosphine]gold(I),97% Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[tri(o-tolyl)phosphine]gold(I) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) XantPhos-Pd-G2