ChemicalBook > Product Catalog >Organic Chemistry >Phosphines >[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Suppliers list
Company Name: Accela ChemBio Inc.
Tel: +1-858-6993322
Email: info@accelachem.com
Products Intro: Product Name:Ethyl 2-Oxo-3-(triphenylphosphoranylidene)propanoate
CAS:13321-61-4
Purity:>=95% Package:0.1g;0.25g;1g;5g;10g;25g
Company Name: Shaanxi Dideu Medichem Co. Ltd
Tel: +86-29-81139210 +86-18192627656
Email: 1059@dideu.com
Products Intro: Product Name:Ethyl (triphenylphosphoranylidene)pyruvate
CAS:13321-61-4
Purity:99% Package:1KG;1USD|25KG;USD|100KG;USD
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196
Email: sale04@alfachem.cn
Products Intro: CAS:13321-61-4
Purity:98% Package:5g; 25g; 100g; 500g; 1kg; 25kg
Company Name: infoark(tianjin) biotechnology Co. Ltd
Tel: 86-13810773243
Email: sales@infoark.com.cn
Products Intro: Product Name:Ethyl(triphenylphosphoranylidene)pyruvate
CAS:13321-61-4
Purity:98%min Package:0.1kg/bottle
Company Name: Aladdin Scientific
Tel:
Email: tp@aladdinsci.com
Products Intro: Product Name:Ethyl (triphenylphosphoranylidene)pyruvate
CAS:13321-61-4
Purity:95% Package:$21.9/1g;$82.9/5g;$318.9/25g;Bulk package Remarks:95%

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE manufacturers
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Basic information
Product Name:[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
Synonyms:[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE;ETHYL (TRIPHENYLPHOSPHORANYLIDENE)PYRUVATE;Ethyl (triphenylphosphoranylidene)pyruvate, [2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane;Ethyl 2-oxo-3-(triphenylphosphoranylidene)propanoate;[(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester;NSC 647346;Ethyl (triphenylphosphoranylidene)pyruvate 95%;[2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane , 95 % min.
CAS:13321-61-4
MF:C23H21O3P
MW:376.38
EINECS:
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents
Mol File:13321-61-4.mol
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Structure
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Chemical Properties
Melting point 175 °C (dec.) (lit.)
Boiling point 524.6±33.0 °C(Predicted)
density 1.20±0.1 g/cm3(Predicted)
storage temp. Store at room temperature
AppearanceOff-white to light yellow Solid
InChIInChI=1S/C23H21O3P/c1-2-26-23(25)22(24)18-27(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,2H2,1H3
InChIKeyOQLOPRPWPANPIE-UHFFFAOYSA-N
SMILESC(OCC)(=O)C(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
WGK Germany 3
HS Code 29310099
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Usage And Synthesis
Chemical Propertiesoff-white to yellow or brown powder
UsesReactant for:
  • Wittig condensation
  • Chemoenzymic preparation of hexafluoroleucine and tetrafluoroleucine

Reactant for synthesis of:
  • Ahiral and chiral cyclic dehydro-α-amino acid derivatives through nucleophilic addition
  • Peptidyl α-keto-based inhibitors of cruzain
  • Deoxyfluoro-L-arabinofuranosyl triazole nucleoside derivatives with antiviral activity
  • Anti-human immunodificiency virus analogs
reaction suitabilityreaction type: C-C Bond Formation
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Preparation Products And Raw materials
Tag:[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE(13321-61-4) Related Product Information
ETHYL 2,4-DIOXO-3-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)PENTANOATE (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE DIETHYL PHENYLPHOSPHONITE