| Company Name: |
Shaanxi Rock New Materials Co., Ltd. Gold
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| Tel: |
0917-15619726767 15619726767 |
| Email: |
liuwei@bjrock.com |
| Products Intro: |
Product Name:Tetrakis(triphenyl phosphite)nickel(0) CAS:14221-00-2 Package:1000g/RMB 22000
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| | TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Basic information |
| | TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Chemical Properties |
| Melting point | 145 °C (dec.)(lit.) | | storage temp. | 2-8°C | | solubility | sol THF, toluene. | | form | solid | | InChI | InChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;/h4*1-15H; | | InChIKey | PGXCIAAANFTEKX-UHFFFAOYSA-N | | SMILES | [Ni].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3.O(P(Oc4ccccc4)Oc5ccccc5)c6ccccc6.O(P(Oc7ccccc7)Oc8ccccc8)c9ccccc9.O(P(Oc%10ccccc%10)Oc%11ccccc%11)c%12ccccc%12 | | EPA Substance Registry System | Nickel, tetrakis(triphenyl phosphite-.kappa.P)-, (T-4)- (14221-00-2) |
| Hazard Codes | Xn | | Risk Statements | 36/37/38-40-43 | | Safety Statements | 26-36/37 | | WGK Germany | 3 | | TSCA | TSCA listed | | HS Code | 29209090 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Carc. 2 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 STOT SE 3 |
| | TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Usage And Synthesis |
| Chemical Properties | white to off-white powder | | Uses | Catalyst for alkene and alkyne hydrocyanation and styrenedimerization | | Preparation | Tetrakis(triphenyl phosphite)nickel(0) can be prepared by treating Nickel(II) Acetylacetonate with Sodium Borohydride and
Triphenyl Phosphite.[1] | | reaction suitability | core: nickel reagent type: catalyst | | storage | Tetrakis(triphenyl phosphite)nickel(0) is a cancer suspect agent; is air sensitive and should be handled using
Schlenk or glove-box techniques. | | References | 1. McLaughlin, J. R. Inorg. Nucl. Chem. Lett. 1973, 9, 565. |
| | TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Preparation Products And Raw materials |
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