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| | 6-Amino-2-naphthalenesulfonic acid Basic information |
| | 6-Amino-2-naphthalenesulfonic acid Chemical Properties |
| density | 1.3588 (rough estimate) | | vapor pressure | 0Pa at 25℃ | | refractive index | 1.6500 (estimate) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | powder to crystal | | pka | -0.08±0.40(Predicted) | | color | White to Light yellow to Light orange | | Water Solubility | 0.12g/L(20 ºC) | | InChI | InChI=1S/C10H9NO3S/c11-9-3-1-8-6-10(15(12,13)14)4-2-7(8)5-9/h1-6H,11H2,(H,12,13,14) | | InChIKey | SEMRCUIXRUXGJX-UHFFFAOYSA-N | | SMILES | C1=C2C(C=C(N)C=C2)=CC=C1S(O)(=O)=O | | LogP | 0.603 at 25℃ | | CAS DataBase Reference | 93-00-5(CAS DataBase Reference) | | EPA Substance Registry System | 6-Amino-2-naphthalenesulfonic acid (93-00-5) |
| Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39 | | WGK Germany | WGK 3 | | TSCA | TSCA listed | | HS Code | 2930909899 | | Storage Class | 11 - Combustible Solids |
| | 6-Amino-2-naphthalenesulfonic acid Usage And Synthesis |
| Description | 2-Aminonaphthalene-6-sulfonic acid [93- 00-5]. (6-aminonaphthalene-2-sulfonic acid), Bronner acid, C10H9NO3S, Mr 223.24, crystallizes from water as the monohydrate in plates although only 0.2 % soluble at 100℃. Sulfonation with 20 % oleum at 20℃ gives a mixture of 1,6- and 6,8-disulfonic acids. | | Uses | 6-Amino-2-naphthalenesulfonic Acid is used in the synthesis of diaryl urea derivatives bearing sulfonamide moiety with an in vitro antitumor activity. | | Definition | ChEBI: 6-aminonaphthalene-2-sulfonic acid is an aminonaphthalenesulfonic acid. | | Production Methods | 2-Hydroxynaphthalene-6-sulfonic acid is aminated by a Bucherer reaction under conditions similar to those used for Tobias acid. | | Flammability and Explosibility | Not classified | | Purification Methods | Crystallise the acid from a large volume of hot water. The diethylamine salt has m 190.5-192o (from EtOH/isoBuOH), and the S-benzylisothiuronium salt has m 330o (from nBuOH). [Beilstein 14 H 760, 14 II 463, 14 III 2249, 14 IV 2804.] |
| | 6-Amino-2-naphthalenesulfonic acid Preparation Products And Raw materials |
| Raw materials | 2-Aminonaphthalene-1-sulfonic acid | | Preparation Products | 1,6-Naphthalenedisulfonic acid-->2-NAPHTHYLAMINE-8-SULFONIC ACID-->BRILLIANT PURPURIN R-->sodium 6-(1-naphthylazo)naphthalene-2-sulphonate-->Brilliant Acid Scarlet G-->NAPHTHALENE SCARLET B-->DIRECT RED 4-->Direct red 72-->C.I. Direct red 74-->2-Naphthalenesulfonic acid, amino[[2-methyl-4-[(2-methylphenyl)azo]phenyl]azo]-, monosodium salt-->Mordant Yellow 3-->Reactive Orange 29-->Reactive Red 84-->vital new red-->5,5'-[3,3'-Dimethyl-1,1'-biphenyl-4,4'-diylbis(azo)]bis[6-aminonaphthalene-2-sulfonic acid sodium] salt-->2-Naphthalenesulfonic acid, 6-[(2-hydroxy-5-methylphenyl)azo]-, monosodium salt-->disodium 4-amino-3-[[4'-[(2-amino-6-sulphonatonaphthyl)azo]-3,3'-dimethyl[1,1'-biphenyl]-4-yl]azo]naphthalene-1-sulphonate-->6-Amino-5-[[4'-[(2-amino-7-sulfo-1-naphtyl)azo]-3,3'-dimethyl-1,1'-biphenyl-4-yl]azo]-2-naphthalenesulfonic acid disodium salt-->Direct Red 73 |
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