|
|
| | SILVER PERCHLORATE HYDRATE Basic information |
| | SILVER PERCHLORATE HYDRATE Chemical Properties |
| Melting point | 43 °C | | density | 2,8 g/cm3 | | storage temp. | Refrigerator (+4°C) | | form | Crystals or Crystalline Powder | | color | White | | Water Solubility | Soluble in water and organic solvents. | | Sensitive | Light Sensitive & Hygroscopic | | Merck | 14,8523 | | Stability: | hygroscopic | | Major Application | PEM fuel cells
material synthesis precursor | | InChI | 1S/Ag.ClHO4.H2O/c;2-1(3,4)5;/h;(H,2,3,4,5);1H2/q+1;;/p-1 | | InChIKey | IXFNJWPLHOWEPT-UHFFFAOYSA-M | | SMILES | O.[Ag].OCl(=O)(=O)=O | | CAS DataBase Reference | 14242-05-8(CAS DataBase Reference) |
| Hazard Codes | O,C | | Risk Statements | 8-34-1 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 1481 5.1/PG 2 | | WGK Germany | 3 | | F | 3-8-10 | | TSCA | Yes | | HazardClass | 5.1 | | PackingGroup | II | | HS Code | 28432900 | | Storage Class | 5.1A - Strongly oxidizing hazardous materials | | Hazard Classifications | Eye Dam. 1
Ox. Sol. 2
Skin Corr. 1B |
| | SILVER PERCHLORATE HYDRATE Usage And Synthesis |
| Chemical Properties | WHITE CRYSTALS OR CRYSTALLINE POWDER | | Uses | Silver Perchlorate Hydrate is used in the hydroxylation of hexabromotetrahydronaphthalene. | | Uses | Silver perchlorate can be used in the manufacturing of explosives. It is generally used as a source of silver ions during silver nanoparticles synthesis. It is used as a catalyst in organic chemistry. | | reaction suitability | reagent type: oxidant | | Purification Methods | Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark. |
| | SILVER PERCHLORATE HYDRATE Preparation Products And Raw materials |
|