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Product Name:2-Methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-aMine
CAS:1026-05-7
Purity:96%Min Package:10g 100g 500g
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| | (2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE Basic information |
| Product Name: | (2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE | | Synonyms: | AKOS BBS-00005674;(2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE;ASISCHEM N44996;N-(2-METHYL-1,2,3,4-TETRAHYDRO-4-QUINOLINYL)-N-PHENYLAMINE;2-Methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-aMine;Quinaldine,4-anilino-1,2,3,4-tetrahydro- (6CI,7CI,8CI);4-Quinolinamine, 1,2,3,4-tetrahydro-2-methyl-N-phenyl-;Propanedinitrile,2-(3-cyano-4,5,5-trimethyl-2(7H)-furanylidene)- | | CAS: | 1026-05-7 | | MF: | C16H18N2 | | MW: | 238.33 | | EINECS: | | | Product Categories: | | | Mol File: | 1026-05-7.mol |  |
| | (2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE Chemical Properties |
| Melting point | 126 °C | | Boiling point | 400.4±44.0 °C(Predicted) | | density | 1.097±0.06 g/cm3(Predicted) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | pka | 4.16±0.60(Predicted) | | Appearance | White to off-white Solid |
| | (2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE Usage And Synthesis |
| Synthesis | General procedure for the synthesis of 2-methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-amine from 2-phenylaminopropionic acid: 2-phenylaminopropionic acid (66 mg, 0.4 mmol) and 4molecular sieves (100 mg) were added to a 10 mL reaction vial, dried with an air pump, and then 200 μL of a reaction vial containing an organic photocatalyst, DPZ (0.28 mg 0.0008 mmol) in toluene solution. Subsequently, 4 mL of purified water was added, the reaction mixture was dried with chloroform, and the mouth of the flask was sealed with a rubber stopper and a balloon filled with dry air was inserted. The reaction flask was placed in a 25°C incubator and the reaction was stirred for 15 h under the illumination of two 1 W blue LEDs. Upon completion of the reaction, about 2/3 of the solvent was removed by distillation using a rotary evaporator. Purification by column chromatography (eluent: hexane/ethyl acetate, 60:30:1) afforded 2-methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-amine (39.1 mg, 82% yield) as a colorless oily liquid. | | References | [1] Patent: CN108017579, 2018, A. Location in patent: Paragraph 0008; 0011; 0012 |
| | (2-METHYL-1,2,3,4-TETRAHYDRO-QUINOLIN-4-YL)-PHENYL-AMINE Preparation Products And Raw materials |
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