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| | CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Basic information |
| Product Name: | CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) | | Synonyms: | C9H7RuCl2(C18H15P);CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)R&;Chloro(indenyl)bis(triphenylphosphine)ruthenium(II),dichloromethaneadduct,min.98%;Chloro(indenyl)bis(triphenylphosphine)rutheniuM(II),dichloroMethane adduct,98%;Ruthenium,chloro[(1,2,3,3a,7a-h)-1H-inden-1-yl]bis(triphenylphosphine)-;Chloro(indenyl)bis(triphenylphosphine)ruthenium(II) may contain <=1 molar equivalent dichloromethane/acetone;CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II),DICHLOROMETHANEADDUCT,MIN.;Chloro-(indenyl)-bis-(triphenylphosphino)-ruthenium | | CAS: | 99897-61-7 | | MF: | C45H37ClP2Ru5* | | MW: | 776.25 | | EINECS: | | | Product Categories: | Ru;organometallic complexes | | Mol File: | 99897-61-7.mol |  |
| | CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Chemical Properties |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | crystal | | color | red-brown | | InChI | 1S/2C18H15P.C9H7.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-5-9-7-3-6-8(9)4-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1 | | InChIKey | AUSVTIHCDLKYHV-UHFFFAOYSA-M | | SMILES | Cl[Ru].[CH]1[CH][C]2C=CC=C[C]2[CH]1.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8 |
| Hazard Codes | Xn | | Risk Statements | 36/37/38-40 | | Safety Statements | 26-36/37/39-36/37 | | WGK Germany | WGK 3 | | TSCA | No | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Carc. 2 Eye Irrit. 2 Skin Irrit. 2 |
| | CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Usage And Synthesis |
| Uses | Catalyst for:
- Single-chain folding of polymers
- Domino redox bicycloisomerization
- Selective radical addition with a designed heterobifunctional halide
- Tandem living radical polymerization via in situ monomer transformation with alcohols
- Atom-economical synthesis of nitrogen heterocycles
Reactant for the synthesis of chiral-at-metal ruthenium allenylidene complexes | | reaction suitability | core: ruthenium reagent type: catalyst |
| | CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Preparation Products And Raw materials |
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