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N,N-Dimethylacrylamide

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CAS:2680-03-7
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Products Intro: Product Name:N,N-Dimethylacrylamide
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N,N-Dimethylacrylamide Basic information
Product Name:N,N-Dimethylacrylamide
Synonyms:Acrylamide, N,N-dimethyl-;Acylamide, N,N-dimethyl;Dimethylamid kyseliny akrylove;dimethylamidkyselinyakrylove;n,n-dimethyl-2-propenamid;Acryloyldimethylamine;N,N-Dimethylpropenamide;N,N-Dimethylacrylamide, 99.5%, stab. with 100ppm 4-methoxyphenol
CAS:2680-03-7
MF:C5H9NO
MW:99.13
EINECS:220-237-5
Product Categories:amine series;Acrylamide and Methacrylamide;Acrylic Monomers;Monomers;Acrylamide and MethacrylamideOrganic Building Blocks;Amides;Carbonyl Compounds
Mol File:2680-03-7.mol
N,N-Dimethylacrylamide Structure
N,N-Dimethylacrylamide Chemical Properties
Melting point 100 °C
Boiling point 80-81 °C/20 mmHg (lit.)
density 0.962 g/mL at 25 °C (lit.)
vapor pressure 65Pa at 20℃
refractive index n20/D 1.473(lit.)
Fp 161 °F
storage temp. 2-8°C(protect from light)
form Liquid
pka-0.77±0.70(Predicted)
color Colorless to Light yellow
Water Solubility Slightly soluble in water (1.000 g/L at 20°C).
FreezingPoint -40℃
Sensitive Light Sensitive
BRN 1742219
Exposure limitsACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
Cosmetics Ingredients FunctionsNOT REPORTED
InChI1S/C5H9NO/c1-4-5(7)6(2)3/h4H,1H2,2-3H3
InChIKeyYLGYACDQVQQZSW-UHFFFAOYSA-N
SMILESCN(C)C(=O)C=C
LogP-0.3 at 23℃
CAS DataBase Reference2680-03-7(CAS DataBase Reference)
NIST Chemistry Reference2-propenamide, N,N-dimethyl(2680-03-7)
EPA Substance Registry System2-Propenamide, N,N-dimethyl- (2680-03-7)
Safety Information
Hazard Codes T,Xn
Risk Statements 21/22-23-36-41
Safety Statements 26-36/37-45-36
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS AU3230000
TSCA TSCA listed
HazardClass 6.1
PackingGroup III
HS Code 29211990
Storage Class6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard ClassificationsAcute Tox. 3 Dermal
Acute Tox. 3 Oral
Eye Dam. 1
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
N,N-Dimethylacrylamide Usage And Synthesis
DescriptionN, N-dimethylacrylamide (DMAA) is an easily polymerized, nonionic monomer. The high reactivity and low initiation temperature of DMAA makes it appropriate for copolymerization. Copolymers of DMAA with N, N-dimethyl-N, and  N-diallyl ammonium chloride (DMDAAC) can be used as polymeric flocculants for water treatment. The unique structure of DMAA shows amelioration in hydrogels for specific applications. DMAA, along with other hydrogels, has a three-dimensional network structure that is capable of retaining water. In addition, DMAA hydrogel can be applied to remove toxic metal ions from wastewater because of its characteristic properties such as chemical stability and high adsorption capacity. DMAA can also be used for flocculation due to its ability to augment the molecular weight of the copolymers[1].
Chemical PropertiesColorless liquid
UsesN,N-Dimethylacrylamide is a useful monomer for synthetic fibers and plastics. It is also used in the synthesis of photoresponsive polymers and copolymers by grafting polysiloxane on the side chain of DMA by homopolymerization or grafting cellulose to form cellulose polymers and copolymerization of methyl methacrylate with DMA or copolymerization of DMA with styrene and butadiene.
UsesDMA is used in the synthesis of photoresponsive polymers. It is used in the synthesis of copolymers by
grafting polysiloxane on the side chain of DMA by homopolymerization or
grafting cellulose to form cellulose polymers and
copolymerization of methyl methacrylate with DMA or
copolymerization of DMA with styrene and butadiene
Synthesis Reference(s)Journal of the American Chemical Society, 79, p. 875, 1957 DOI: 10.1021/ja01561a024
General DescriptionN,N-Dimethylacrylamide (DMA) is a nonionic acrylic monomer that can make swellable polymeric particles.
References[1] Ayatzhan Akhmetzhan. “A Short Review on the N,N-Dimethylacrylamide-Based Hydrogels.” Gels 7 4 (2021).
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