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| | TERRETONIN Basic information |
| Product Name: | TERRETONIN | | Synonyms: | TERRETONIN;6,9-Dihydroxy-4,4,8,17-tetramethyl-12-methylene-3,7,15,17a-tetraoxo-D-homo-16-oxaandrost-5-ene-17α-carboxylic acid methyl ester;TERRETONIN(RG);(+)-territonin;2H-Phenanthro[1,2-c]pyran-2-carboxylic acid, 1,4,4a,4b,5,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-6,10b-dihydroxy-2,4b,7,7,10a,12a-hexamethyl-12-methylene-1,4,5,8-tetraoxo-, methyl ester, (2S,4aS,4bR,10aR,10bR,12aS)- | | CAS: | 71911-90-5 | | MF: | C26H32O9 | | MW: | 488.53 | | EINECS: | | | Product Categories: | | | Mol File: | 71911-90-5.mol |  |
| | TERRETONIN Chemical Properties |
| Melting point | 260～262℃ | | Boiling point | 676.7±55.0 °C(Predicted) | | density | 1.35±0.1 g/cm3(Predicted) | | pka | 8.26±0.70(Predicted) |
| | TERRETONIN Usage And Synthesis |
| Uses | Terretonin is a fungal terpenoid isolated from Aspergillus terreus. The complete biosynthetic pathway of terretonin includes: cytochrome P450 Trt6 catalyzes the oxidation of terrenoid to obtain an unstable intermediate; then it is catalyzed by isomerase Trt14 and processed by non-heme iron-dependent dioxygenase Trt7 to complete the biosynthesis of terretonin[1]. | | Definition | ChEBI: A tetracyclic meroterpenoid that is isolated from Aspergillus terreus. | | References | [1] Matsuda Y, et al. Uncovering the unusual D-ring construction in terretonin biosynthesis by collaboration of a multifunctional cytochrome P450 and a unique isomerase[J]. Journal of the American Chemical Society, 2015, 137(9): 3393-3401. |
| | TERRETONIN Preparation Products And Raw materials |
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