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| | VINYLBENZYL ALCOHOL Basic information |
| | VINYLBENZYL ALCOHOL Chemical Properties |
| Boiling point | 101-102 °C/12 mmHg (lit.) | | density | 1.021 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.54(lit.) | | Fp | 202 °F | | form | liquid | | InChI | 1S/C9H10O/c1-2-9(10)8-6-4-3-5-7-8/h2-7,9-10H,1H2 | | InChIKey | MHHJQVRGRPHIMR-UHFFFAOYSA-N | | SMILES | OC(C=C)c1ccccc1 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | VINYLBENZYL ALCOHOL Usage And Synthesis |
| Uses | α-Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols. | | Uses | αVinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 52, p. 3524, 1987 DOI: 10.1021/jo00392a006 | | General Description | α-Vinylbenzyl alcohol is an allyl alcohol derivative. Its isomerization reaction using a novel ternary catalyst system has been reported. The kinetic resolution of racemic α-vinylbenzyl alcohol by tungsten-catalyzed asymmetric epoxidation method has been repoorted. The coupling reaction of α-vinylbenzyl alcohol and aldehydes in the presence of RuCl2(PPh3)3 catalyst and In(OAc)3 as a co-catalyst in ionic liquids has been investigated. Etherification reaction of glycerol with α-vinylbenzyl alcohol in the presence of sulfonic catalyst immobilized on silica (SiO2–SO3H) has been reported. |
| | VINYLBENZYL ALCOHOL Preparation Products And Raw materials |
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