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| | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine Basic information |
| Product Name: | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine | | Synonyms: | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine;2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl,min.98%VPhos;2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl, Vphos;2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-buty;2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl;Dicyclohexyl(2',4'-di-tert-butyl-6'-methoxy-[1,1'-biphenyl]-2-yl)phosphane;2-Dicyclohexylphosphino-2′-methoxy-4′,6′-di-tert-butylbiphenyl;phosphino-2'-methoxy-4',6'-di-t-butyL | | CAS: | 1848244-75-6 | | MF: | C33H49OP | | MW: | 492.72 | | EINECS: | | | Product Categories: | Buchwald Ligands&Precatalysts;Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series | | Mol File: | 1848244-75-6.mol | ![[2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine Structure](CAS/20180703/GIF/1848244-75-6.gif) |
| | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine Chemical Properties |
| Melting point | 113-118 °C | | Boiling point | 561.5±50.0 °C(Predicted) | | storage temp. | Inert atmosphere,Store in freezer, under -20°C | | form | solid | | color | white to off-white | | InChI | 1S/C33H49OP/c1-32(2,3)24-22-28(33(4,5)6)31(29(23-24)34-7)27-20-14-15-21-30(27)35(25-16-10-8-11-17-25)26-18-12-9-13-19-26/h14-15,20-23,25-26H,8-13,16-19H2,1-7H3 | | InChIKey | LYVFKWGKMKCNPE-UHFFFAOYSA-N | | SMILES | P(C1=CC=CC=C1C1=C(OC)C=C(C(C)(C)C)C=C1C(C)(C)C)(C1CCCCC1)C1CCCCC1 |
| WGK Germany | WGK 3 | | Storage Class | 11 - Combustible Solids |
| | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine Usage And Synthesis |
| Uses | As the Pd G4 complex, this ligand from the Buchwald group offers best-in-class performance in the micellar aqueous Negishi coupling of heterocyclic alkyl bromides. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reaction type: Cross Couplings reagent type: ligand reaction type: click chemistry |
| | [2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine Preparation Products And Raw materials |
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