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| | Bismuth(III) trifluoromethanesulfonate Basic information | | Uses |
| | Bismuth(III) trifluoromethanesulfonate Chemical Properties |
| Melting point | 300 °C | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide. | | form | Liquid | | color | Clear colorless | | Sensitive | Hygroscopic | | Hydrolytic Sensitivity | 5: forms reversible hydrate | | Stability: | hygroscopic | | InChI | InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 | | InChIKey | HIYUMYXSGIKHHE-UHFFFAOYSA-M | | SMILES | C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Bi+3] |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-24/25 | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | No | | HazardClass | 8 | | HS Code | 29049090 | | Storage Class | 11 - Combustible Solids |
| | Bismuth(III) trifluoromethanesulfonate Usage And Synthesis |
| Uses | Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions.
| | Chemical Properties | White powder | | Uses | Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides. | | Uses | Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions. | | Uses | Catalyst for organic syntheses. | | reaction suitability | core: bismuth
reagent type: catalyst |
| | Bismuth(III) trifluoromethanesulfonate Preparation Products And Raw materials |
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