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Postion:Product Catalog >Organic Chemistry>Amides>ForMaMidiniuM Iodide
ForMaMidiniuM Iodide
  • ForMaMidiniuM Iodide
  • ForMaMidiniuM Iodide

ForMaMidiniuM Iodide

Price $200
Package 1KG
Min. Order: 1KG
Update Time: 2019-07-06

Product Details

Product Name: ForMaMidiniuM Iodide CAS No.: 879643-71-7
Min. Order: 1KG Purity: 99%
Supply Ability: customise Release date: 2019/07/06

Product number: WM0071

Article illustration

Product specifications:

ForMaMidiniuM Iodide Basic information
Applications
Product Name: ForMaMidiniuM Iodide
Synonyms: ForMaMidiniuM Iodide;HC(NH2)2I(FAI);Formamidine Hydroiodide;Formamidine hydriodide;Formamidine Hydroiodide (Low water content);Imidoformamide hydroiodide (1:1);Formamidinium iodide (FAI)
CAS: 879643-71-7
MF: CH5IN2
MW: 171.96827
EINECS: -0
Product Categories:  
Mol File: 879643-71-7.mol
Article illustration
 
ForMaMidiniuM Iodide Chemical Properties
 
Safety Information
Safety Statements  24/25
MSDS Information
 
 
ForMaMidiniuM Iodide Usage And Synthesis
Applications Formamidinium lead iodide shows a narrower bandgap than the commonly used methylammonium lead iodide (1.48 eV compared to ~1.57 eV), and hence lies closer to that favourable for optimum solar conversion efficiencies. Spin-coating the formamidinium iodide (FAI) plus PbI2 precursor solution in N,N-dimethylformamide (DMF) initially resulted in discontinuous perovskite films. However, by adding a small amount of hydroiodic acid (HI) to the stoichiometric FAI, extremely uniform and continuous films were formed.
Controlled humidity is another deciding factor that affects the film morphology, crystallinity, and optical and electrical properties of FAPbI3 [2]. 16.6% PCE was achieved with low relative humidity of 2%, with the device efficiency dropped to about half (8.6%) when the humidity was 40%.
Low-volatility additives such as FACl and MACl are good candidates for assisting in the crystallisation of phase pure α-FAPbI3 via the formation of intermediate mixtures, which prohibits the crystallisation of the δ-FAPbI3 phase. It also has been observed that the black perovskite-type polymorph (α-phase), which is stable at relatively high temperatures (above 160 oC), turned into the yellow FAPbI3 polymorph (δ-phase) in an ambient humid atmosphere. Results show that incorporation of MAPbBr3 into FAPbI3 stabilises the perovskite phase of FAPbI3 and improves the power conversion efficiency of the solar cell to more than 18% under a standard illumination of 100 mW/cm2.
With an approach of FAPbI3 crystallisation by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide, device with performance over 20% has been fabricated.

 

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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