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Postion:Product Catalog >Organic Chemistry>Phosphines>Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate
  • Tri-tert-butylphosphine tetrafluoroborate
  • Tri-tert-butylphosphine tetrafluoroborate

Tri-tert-butylphosphine tetrafluoroborate

Price $1
Package 1KG
Min. Order: 1G
Supply Ability: 1MT
Update Time: 2019-07-06

Product Details

Product Name: Tri-tert-butylphosphine tetrafluoroborate CAS No.: 131274-22-1
Min. Order: 1G Purity: 99%
Supply Ability: 1MT Release date: 2019/07/06

AD68

Tri-tert-butylphosphine tetrafluoroborate Basic information
Reaction
Product Name: Tri-tert-butylphosphine tetrafluoroborate
Synonyms: Tri-t-butylphosphoniumtetrafluoroborate,99%;fluoroboric acid tri-tert-butylphosphine adduct;tri-tert-butylphosphine fluoroboric acid adduct;Tri-tert-butylphosphonium tetrafluoroborate, 97+%;Tri-tert-butylphosphonium tetrafluoroborate,99%;Tri-tert-butylphosphoniuM tetrafluoroborate, 97+% 1GR;Tri-tert-butylphosphine tetrafluoborate;Tri-tert-butylphosphoniuM tetr
CAS: 131274-22-1
MF: C12H28P.BF4
MW: 290.13
EINECS: -0
Product Categories: Ligand;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds;organometallic complex;Organophosphine salt;Achiral Phosphine;Alkyl Phosphine;P-BF4
Mol File: 131274-22-1.mol
Article illustration
 
Tri-tert-butylphosphine tetrafluoroborate Chemical Properties
Melting point  261 °C(lit.)
form  Crystals and Chunks
color  White
Water Solubility  Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
Sensitive  Hygroscopic
BRN  8813613
InChIKey YSTLBJVHZMEEAC-UHFFFAOYSA-N
CAS DataBase Reference 131274-22-1(CAS DataBase Reference)
 
Safety Information
Hazard Codes  Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  22-24/25-36/37/39-26
RIDADR  UN 1759 8/PG III
WGK Germany  3
HazardClass  8
PackingGroup  III
 
 
Tri-tert-butylphosphine tetrafluoroborate Usage And Synthesis
Reaction
  1. Air-stable, non-pyrophoric precursor of the Tri-t-butylphosphine ligand which is used in a variety of catalytic processes.
  2. Ligand for Suzuki cross-couplings.
  3. Ligand for Heck Reactions.
  4. Ligand for Stille Cross-couplings.
  5. Ligand for α-Arylation and vinylation of arylmandelic acid derivatives.
  6. Ligand for direct arylation of hetercycles
  7. Synthesis of benzocyclobutenes by C-H activation.
  8. Cross-coupling of Grignard reagents and aryl bromides.
  9. Palladium catalyzed annulation of haloanilines.
  10. Palladium-Catalyzed Acylation.
  11. Palladium Catalyzed Carbonylative Heck Reaction.
  12. Palladium-catalyzed aminosulfonylation.
  13. Palladium-catalyzed intramolecular C–O bond formation.
  14. Ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acid.
Article illustration
Article illustration
Article illustration
Article illustration
Chemical Properties white to light yellow crystal powde
Uses suzuki reaction
 
 

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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  • Since: 2014-12-17
  • Address: Zhengzhou High tech Zone, Henan Province, China
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