(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8) 1H NMR
Product Name(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
CAS104372-31-8
Molecular FormulaC10H15NO3S
Molecular Weight229.3
InChIInChI=1/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9-,10?,11?/s3
InChIKey GBBJBUGPGFNISJ-SENRVMEJNA-N
SmilesC123C[C@@]4([H])CC[C@@]1(CS(=O)(=O)N2O3)C4(C)C |&1:2,6,r|
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MassMS-IW-4931 (-)-(2S,8aR)-(camphorsulfonyl)oxaziridine C10H15NO3S (Mass of molecular ion: 229)
Source Temperature: 140 °C Sample Temperature: 130 °C Direct, 75 eV
15.0 1.4 18.0 3.7 26.0 1.2 27.0 21.9 28.0 7.0 29.0 13.5 30.0 2.6 32.0 1.0 38.0 1.8 39.0 37.8 40.0 9.1 41.0 66.9 42.0 14.6 43.0 38.4 44.0 2.7 48.0 7.3 50.0 2.9 51.0 10.2 52.0 6.4 53.0 28.9 54.0 13.1 55.0 39.6 56.0 6.6 57.0 11.2 58.0 1.8 59.0 3.6 63.0 3.3 64.0 13.5 65.0 14.6 66.0 8.2 67.0 64.9 68.0 15.5 69.0 37.5 70.0 8.0 71.0 1.3 73.0 1.0 77.0 30.0 78.0 7.3 79.0 44.2 80.0 17.4 81.0 31.2 82.0 35.6 83.0 8.2 84.0 2.2 85.0 1.2 91.0 37.6 92.0 9.0 93.0 92.5 94.0 36.4 95.0 18.1 96.0 6.2 97.0 11.0 98.0 1.1 103.0 1.9 104.0 3.7 105.0 15.4 106.0 18.5 107.0 43.1 108.0 100.0 109.0 56.4 110.0 7.7 111.0 1.6 117.0 3.1 118.0 2.5 119.0 6.0 120.0 9.8 121.0 7.4 122.0 59.2 123.0 20.6 124.0 4.9 131.0 2.3 132.0 6.4 133.0 5.5 134.0 34.5 135.0 14.2 136.0 8.3 137.0 6.1 138.0 1.8 146.0 2.8 147.0 2.4 148.0 23.9 149.0 14.0 150.0 17.9 151.0 3.4 152.0 1.0 164.0 8.4 165.0 14.4 166.0 1.7 167.0 1.0 186.0 4.0 199.0 2.7 201.0 11.1 202.0 1.2 229.0 4.8
400 MHz in CDCl3
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1H NMR 399.65 MHz C10 H15 N O3 S 0.039 g : 0.5 ml CDCl3 (-)-(2S,8aR)-(camphorsulfonyl)oxaziridine 
Assign. Shift(ppm)
A *1 3.294 B *1 3.113 C 2.632 D 2.136 E 2.02 F 1.99 G 1.92 J 1.780 K 1.52 L *2 1.175 M *2 1.039 ASSIGNED BY H-H AND C-H COSY. J(A,B)=-14.0HZ J(C,J)=-15.5HZ J(C,D)=4.5HZ J(C,F)=-2.8HZ J(D,F)=4.5HZ
Hz ppm Int.1324.83 3.315 229 1310.79 3.280 326 1250.12 3.129 277 1236.08 3.093 193 1063.48 2.662 54 1060.67 2.654 50 1058.96 2.650 52 1056.03 2.643 47 1047.97 2.623 60 1045.17 2.616 56 1043.33 2.611 56 1041.87 2.607 35 1040.53 2.604 51 857.91 2.147 59 853.76 2.137 112 850.95 2.130 56 849.37 2.126 63 816.04 2.042 65 812.62 2.034 55 807.01 2.020 85 805.05 2.015 113 804.32 2.013 109 803.10 2.010 101 801.64 2.006 62 800.54 2.004 50 798.83 1.999 53 795.78 1.992 64 791.99 1.982 54 785.28 1.965 35 782.35 1.958 56 780.76 1.954 57 779.05 1.950 70 777.22 1.945 32 769.41 1.926 70 768.43 1.923 87 766.11 1.917 40 760.38 1.903 61 718.99 1.800 207 703.49 1.761 190 616.46 1.543 35 611.57 1.531 64 608.40 1.523 91 599.24 1.500 50 469.73 1.176 937 415.41 1.040 1000
KBr disc
nujol mull
