18368-76-8

2-氯-3-甲基吡啶(18368-76-8)質(zhì)譜(MS)

產(chǎn)品名稱:2-氯-3-甲基吡啶

CAS:18368-76-8

分子式:C6H6ClN

分子量: 127.57

¹HNMR

¹³CNMR

IR1

Mass

MS2006-02927WA      
2-chloro-3-methylpyridine
C6H6ClN             (Mass of molecular ion:    127)

   Source Temperature: 250 °C
   Sample Temperature: 250 °C
   Reservoir, 70 eV

      18.0       1.0
      26.0       1.6
      27.0       1.9
      37.0       4.2
      38.0       7.4
      39.0      20.8
      40.0       2.7
      41.0       2.3
      49.0       1.2
      50.0       3.8
      51.0       4.4
      52.0       2.8
      61.0       2.7
      62.0       4.5
      62.5       1.3
      63.0      12.4
      63.5       1.1
      64.0      17.0
      65.0      36.1
      66.0       5.7
      73.0       2.6
      75.0       1.6
      76.0       1.7
      90.0       4.0
      91.0      89.3
      92.0      56.1
      93.0       3.8
      99.0       2.8
     100.0       1.3
     101.0       1.4
     126.0       5.8
     127.0     100.0
     128.0       8.6
     129.0      32.0
     130.0       2.2

in CDCl3

parameter in CDCl3

¹H NMR	300 MHz
C₆ H₆ Cl N	20 % in CDCl₃
2-chloro-3-methylpyridine

    Parameter     ppm  Hz

      D(A)         8.18
      D(B)         7.08
      D(C)         7.52
      D(D)         2.30
       J(A,B)          4.8
       J(A,C)          2.2
       J(A,D)          0.6
       J(B,C)          7.8
       J(B,D)          0.3
       J(C,D)          0.8
     
     BELL,C.L. ET AL. J.HETEROCYCL.CHEM. 2, 420 (1965)

     Hz     ppm     Int.

   2457.83   8.193     87
   2457.28   8.191     91
   2455.64   8.185     95
   2455.09   8.184     93
   2453.02   8.177     94
   2452.47   8.175     96
   2450.83   8.169     95
   2450.28   8.168     92
   2261.50   7.538     76
   2260.73   7.536     83
   2260.08   7.534     67
   2259.37   7.531     81
   2258.55   7.528     75
   2253.73   7.512     85
   2252.91   7.510     92
   2252.20   7.507     75
   2251.55   7.505     91
   2250.78   7.503     84
   2130.20   7.101    131
   2125.38   7.085    131
   2122.43   7.075    115
   2117.62   7.059    109
    690.05   2.300   1000

in CDCl3