亞硝基苯(586-96-9)Raman光譜
InChI:InChI=1S/C6H5NO/c8-7-6-4-2-1-3-5-6/h1-5H
InChIKey: NLRKCXQQSUWLCH-UHFFFAOYSA-N
Smiles:C1(N=O)=CC=CC=C1
90 MHz in CDCl3
parameter in CDCl3
-
| 1H NMR |
89.56 MHz |
| C6 H5 N O
|
0.040 g : 0.5 ml CDCl3
|
| nitrosobenzene
|
 |
Assign. Shift(ppm)
A 7.907
B 7.20 to 7.75
|
Hz ppm Int.
711.81 7.948 343
709.88 7.927 419
708.19 7.908 240
707.19 7.897 232
706.81 7.893 229
704.56 7.867 490
702.06 7.839 782
700.50 7.822 203
698.25 7.797 118
696.25 7.775 79
691.50 7.722 174
690.50 7.710 241
688.63 7.690 194
687.31 7.675 546
685.94 7.660 1000
684.00 7.638 495
683.06 7.627 398
680.44 7.598 292
678.63 7.578 460
676.56 7.555 164
675.13 7.539 137
673.56 7.521 162
672.00 7.504 112
670.06 7.482 118
-
| 1H NMR |
300 MHz |
| C6 H5 N O
|
10 wt% in CCl4
|
| nitrosobenzene
|
|
Parameter ppm Hz
D(A) 7.813
D(B) 7.547
D(C) 7.610
J(A,A') 1.97
J(A,B) 7.91
J(A,B') 0.56
J(A,C) 1.28
J(A',B) 0.56
J(A',B') 7.91
J(A',C) 1.28
J(B,B') 1.36
J(B,C) 7.41
J(B',C) 7.41
CASTELLANO,S. ET AL. TETRAHEDRON LETT. 1967, 5205
|
Hz ppm Int.
2351.34 7.838 77
2348.94 7.830 582
2347.57 7.825 715
2345.96 7.820 385
2342.96 7.810 255
2340.82 7.803 1000
2339.20 7.797 726
2292.99 7.643 61
2291.56 7.639 123
2290.11 7.634 79
2287.54 7.625 89
2284.29 7.614 443
2281.70 7.606 148
2278.82 7.596 318
2277.27 7.591 532
2275.67 7.586 252
2272.81 7.576 151
2271.18 7.571 589
2270.45 7.568 845
2269.06 7.564 377
2264.99 7.550 387
2264.48 7.548 391
2263.10 7.544 848
2261.33 7.538 187
2257.89 7.526 140
2256.22 7.521 289
2254.57 7.515 182
ANION RADICAL, ELECTROLYTIC REDUCTION IN CH3CN
OXIDATION WITH AIBN IN TOLUENE
OXID. OF PHENOL
ANION RADICAL, ELECTRORED. IN LIQ. NH3
OXIDATION WITH AIBN IN BENZENE
CATION RADICAL, ELECTROLYSIS IN CH3CN-CH3NO2
ANION RADICAL, REACTION WITH (C6H5)NH(OH)