82358-61-0

氰甲基三正丁基氯化(82358-61-0)質(zhì)譜(MS)

產(chǎn)品名稱:氰甲基三正丁基氯化

CAS:82358-61-0

分子式:C14H29ClNP

分子量: 277.81

Mass

MS-IW-8385          
tributyl(cyanomethyl)phosphonium chloride
C14H29ClNP          (Mass of molecular ion:    277)

   Source Temperature: 170 °C
   Sample Temperature: 170 °C
   Direct, 75 eV

      17.0       1.4
      18.0       7.9
      26.0       2.5
      27.0      12.4
      28.0       7.9
      29.0      35.5
      30.0       1.0
      35.0       3.3
      36.0      37.3
      37.0       1.2
      38.0      12.4
      39.0      10.9
      40.0       3.2
      41.0      46.6
      42.0       4.5
      43.0       4.5
      44.0       1.3
      45.0       4.4
      46.0       1.9
      47.0       4.9
      48.0       2.8
      49.0       1.2
      50.0       1.0
      51.0       1.8
      52.0       1.1
      53.0       4.3
      54.0       8.5
      55.0      29.9
      56.0      10.1
      57.0      11.6
      58.0       2.3
      59.0       9.7
      60.0       2.7
      61.0      30.1
      62.0      33.9
      63.0       3.2
      67.0       2.2
      68.0       1.2
      69.0       3.1
      70.0       1.5
      71.0       5.7
      72.0      37.0
      73.0      13.0
      74.0       4.8
      75.0      12.5
      76.0     100.0
      77.0       5.0
      78.0       6.4
      81.0       1.7
      82.0       1.9
      83.0       6.6
      85.0       3.8
      86.0       7.4
      87.0      30.1
      88.0       9.0
      89.0       9.3
      90.0      48.2
      91.0       3.2
      92.0       7.8
      95.0       1.3
      96.0       4.2
      97.0       2.3
      98.0       1.4
      99.0       2.7
     100.0      10.2
     101.0      94.3
     102.0      17.9
     103.0      10.7
     104.0      17.1
     105.0       2.0
     113.0       2.4
     114.0       7.8
     115.0      43.5
     116.0      27.0
     117.0       5.3
     118.0      21.9
     119.0       1.7
     120.0       3.5
     126.0       1.4
     127.0       1.7
     128.0      58.1
     129.0      38.3
     130.0       9.6
     131.0      14.8
     132.0       4.0
     134.0       2.3
     140.0       1.0
     141.0       1.1
     142.0       8.8
     143.0      36.0
     144.0       4.8
     145.0      14.8
     146.0       6.8
     147.0       2.5
     156.0      24.0
     157.0      18.6
     158.0       7.7
     159.0       2.4
     160.0       8.8
     161.0       2.3
     162.0       2.1
     170.0      18.5
     171.0       4.8
     173.0       8.1
     174.0       1.9
     184.0      19.1
     185.0      18.5
     186.0       4.0
     187.0      13.3
     188.0       1.6
     189.0       3.0
     198.0       1.2
     199.0       2.4
     201.0       1.3
     202.0       5.4
     203.0       1.2
     212.0      45.6
     213.0       6.9
     226.0       6.1
     240.0      11.5
     241.0      49.5
     242.0      15.2
     243.0       1.8

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₄ H₂₉ Cl N P	0.046 g : 0.5 ml CDCl₃
tributyl(cyanomethyl)phosphonium chloride

    Assign.     Shift(ppm)

      A             5.061
      B             2.679
      C             1.681
      D             1.557
      E             1.001

     Hz     ppm     Int.

   2030.52   5.081    140
   2014.89   5.042    139
   1086.18   2.718     98
   1080.69   2.705     61
   1077.64   2.697     80
   1072.75   2.685    139
   1069.46   2.676    142
   1064.70   2.665     84
   1062.13   2.658     63
   1058.59   2.649     46
   1056.03   2.643    113
    686.28   1.718     61
    684.94   1.714     63
    678.47   1.698    113
    674.07   1.687     84
    670.65   1.679    128
    665.77   1.666     68
    662.48   1.658     98
    659.67   1.651     50
    654.42   1.638     38
    639.89   1.602     38
    632.69   1.584    134
    625.37   1.565    216
    618.04   1.547    202
    610.84   1.529    109
    407.10   1.019    496
    399.90   1.001   1000
    392.58   0.983    466

in CDCl3