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Organic Letters

Organic Letters

IF: 4.9
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100 Selective Oxygenation of p-Xylene to p-Tolualdehyde via Photoinduced Electron Transfer

Published:14 October 2000 DOI: 10.1021/ol0065571 PMID: 11073666
Kei Ohkubo, Shunichi Fukuzumi

Abstract

The 100% selective oxygenation of p-xylene to p-tolualdehyde is initiated by photoinduced electron transfer from p-xylene to the singlet excited state of 10-methyl-9-phenylacridinium ion under visible light irradiation, yielding p-tolualdehyde exclusively as the final oxygenated product. The reason for the high selectivity in the photocatalytic oxygenation of p-xylene is discussed on the basis of the photoinduced electron transfer mechanism.

Substances (3)

Related products
Procduct Name CAS Molecular Formula Supplier Price
p-Tolualdehyde 104-87-0 C8H8O 643 suppliers $6.00-$6310.57
P-XYLENE 106-42-3 C8H10 468 suppliers $7.62-$6320.00
10-Methyl-9-phenylacridinium Perchlorate, 1 g - Inquiry

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