By free radical polymerizing methylacrylylethyl trimethyl ammonium chloride (DMC), styrene (ST), and methoxy polyethylene glycol acrylate (MPEGA), a novel type of hydrophilic polymer antistatic agent (PDSM) was created. By utilizing FT-IR and ¹H NMR, the structure and properties of the PDSM copolymer were investigated. By using the melt blending approach, composites made of ABS (acrylonitrile-styrene-butadiene copolymer)/PDSM were generated. The composites’ mechanical characteristics and surface resistivity were measured. The results indicated that PDSM was evenly dispersed on the inner surface of ABS resin, resulting in a continuous conductive network, and serving the intended function of long-lasting antistatic. The surface resistance of ABS composites could be greatly decreased using the PDSM copolymer antistatic agent. Surface resistivity of ABS/PDSM composites were around 10⁹-10¹⁰ Ω when the proportion of PDSM copolymer was up to 15 wt%. As MPEGA concentration increased, the surface resistivity of ABS/PDSM materials declined because MPEGA comprised hydrophilic ether bonds and flexible side chains.