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Journal of Environmental Sciences-china

Journal of Environmental Sciences-china

IF: 5.9
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Removal of heavy metals from a contaminated soil using tartaric acid.

Published:1 January 2006 DOI: PMID: 17078552
Xin Ke, Pei-jun Li, Qi-xing Zhou, Yun Zhang, Tie-heng Sun

Abstract

This study reports the feasibility of remediation of a heavy metal (HM) contaminated soil using tartaric acid, an environmentally-friendly extractant. Batch experiments were performed to test the factors influencing remediation of the HM contaminated soil. An empirical model was employed to describe the kinetics of HM dissolution/desorption and to predict equilibrium concentrations of HMs in soil leachate. The changes of HMs in different fractions before and after tartaric acid treatment were also investigated. Tartaric acid solution containing HMs was regenerated by chestnut shells. Results show that utilization of tartaric acid was effective for removal of HMs from the contaminated soil, attaining 50%-60% of Cd, 40%-50% of Pb, 40 %-50% of Cu and 20%-30% of Zn in the pH range of 3.5-4.0 within 24 h. Mass transfer coefficients for cadmium (Cd) and lead (Pb) were much higher than those for copper (Cu) and zinc (Zn). Sequential fractionations of treated and untreated soil samples showed that tartaric acid was effective in removing the exchangeable, carbonate fractions of Cd, Zn and Cu from the contaminated soil. The contents of Pb and Cu in Fe-Mn oxide fraciton were also significantly decreased by tartaric acid treatment. One hundred milliliters of tartaric acid solution containing HMs could be regenerated by 10 g chestnut shells in a batch reactor. Such a remediation procedure indicated that tartaric acid is a promising agent for remediation of HM contaminated soils. However, further research is needed before the method can be practically used for in situ remediation of contaminated sites.

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Procduct Name CAS Molecular Formula Supplier Price
DL-Tartaric acid 133-37-9 C4H6O6 820 suppliers $7.00-$2752.94
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Lead 7439-92-1 Pb 318 suppliers $10.00-$14900.00
GAMMA-CYCLODEXTRIN HYDRATE 91464-90-3 C48H82O41 47 suppliers $10.00-$883.49

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