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ACS Applied Bio Materials

ACS Applied Bio Materials

IF: 4.6
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Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests.

Published:19 June 2013 DOI: 10.3762/bjoc.9.133 PMID: 23843912
Sophie Fourmentin, Anca Ciobanu, David Landy, Gerhard Wenz

Abstract

The inclusion of volatile derivatives of benzene and cyclohexane in β-cyclodextrin (β-CD), hydroxypropyl-β-CD, and hydrophilic β-CD-thioethers was investigated by static headspace gas chromatography (HS-GC) and molecular modelling. The obtained binding constants strongly increase with the amount of space filling of the CD cavity and the salt concentration. β-CD thioethers show a 3-10 times higher binding potential than native β-CD.

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