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Dermatitis

Dermatitis

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Nonoccupational Allergic Contact Dermatitis to 4-Acryloylmorpholine in Smartwatch Screen Protectors Glue

Published:8 June 2022 DOI: 10.1097/DER.0000000000000888
M. Gatica-Ortega,?M. Mowitz,?F. Navarro-Trivi?o,?A. B. Gargallo-Quintero,?Lidia Carbonero-Jiménez,?F. Heras‐Mendaza,?Francisca Herreros-Montejano,?T. Sanz-Sánchez,?L. Borrego,?M. Bruze,?C. Svedman,?M. Pastor-Nieto

Abstract

Background We recently identified an outbreak of occupational allergic contact dermatitis (ACD) involving workers of a Spanish company selling smartphone protective cases from a glue product. A chemical analysis of one glue sample revealed the presence of 4-acryloylmorpholine among other allergens. The same glue is also used to attach tempered glass protective cases to Apple smartwatches. Objective Our objective was to describe a case series of nonoccupational consumer ACD from the previously mentioned Apple smartwatch protective case glue. Methods We evaluated epidemiological and clinical data, as well as patch tests results. Results Three women were diagnosed with nonoccupational ACD from the adhesive. An annular vesicular inflammatory plaque involving the dorsal aspect of the wrist was initially observed in all. Two of the 3 patients were patch tested with 4-acryloylmorpholine 0.5% with positive strong reactions. Both also strongly reacted to a sample of the glue semiopen tested in a drop of petrolatum. One of them was also positive for various acrylates. Conclusions 4-Acryloylmorpholine has been identified in an adhesive used to attach protective cases to smartwatches. Nonoccupational ACD have been described to involve consumers of smartwatches. A UV-curable adhesive used to attach protective cases to smartwatches has been considered to be the culprit.

Substances (1)

Related products
Procduct Name CAS Molecular Formula Supplier Price
4-Acryloylmorpholine 5117-12-4 C7H11NO2 330 suppliers $6.00-$2814.52

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