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Reaction Kinetics, Mechanisms and Catalysis

Reaction Kinetics, Mechanisms and Catalysis

IF: 1.7
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Synthesis of acetone oxime through acetone ammoximation over TS-1

Published:1 July 2004 DOI: 10.1023/B:REAC.0000034845.65961.3e
Xinhua Liang, Zhentao Mi, Yaquan Wang, Li Wang, Xiangwen Zhang

Abstract

The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.

Substances (4)

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Acetone oxime 127-06-0 C3H7NO 534 suppliers $5.68-$1520.00
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Pramipexole Imine 1 suppliers Inquiry
3-Ethoxy-4-methoxybenzaldehyde hydrazone 1177111-23-7 - Inquiry

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