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Journal of Power Sources

Journal of Power Sources

IF: 8.09
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Conductivities of 1,2-dimethoxyethane or 1,2-dimethoxyethane-related solutions of lithium salts

Published:5 January 1993 DOI: 10.1016/0378-7753(93)85006-A
M. Yoshio, H. Nakamura, M. Hyakutake, S. Nishikawa, K. Yoshizuka

Abstract

Conductometric studies of highly-concentrated solutions of lithium salts have been carried out in 1,2-dimethoxyethane (DME), a low dielectric and high DN (donor number) solvent. The formation constant of the triple ion has been determined and discussed with respect to that obtained from the measurement in a very dilute solution. Direct determination of the molar conductivity of the triple ion pair has been done and compared to conventionally assumed values. The reason for the increase in the conductivity of Li ion containing propylene carbonate (PC) solutions with the addition of DME is discussed. Preferential solvation of the Li ion by solvents with higher DN is proposed as one important factor. The solvation constants of Li ion by solvents with high DN have been determined.

Substances (6)

Related products
Procduct Name CAS Molecular Formula Supplier Price
Propylene carbonate 108-32-7 C4H6O3 783 suppliers $6.35-$10140.00
1,2-Dimethoxyethane 110-71-4 C4H10O2 564 suppliers $13.00-$5450.00
Lithium ion (1+) 17341-24-1 Li+ 56 suppliers Inquiry
LITHIUM IODATE 13765-03-2 ILiO3 55 suppliers $29.12-$2546.78
MOLYBDENUM TETRACHLORIDE DIMETHOXYETHANE COMPLEX 134535-29-8 C4H10Cl4MoO2 8 suppliers Inquiry
1,2-Dimethoxyethane 143585-58-4 C4H10O2 8 suppliers $130.00-$130.00

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