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Inorganic Chemistry

Inorganic Chemistry

IF: 4.3
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Dendrimer-Encapsulated Pd Nanoparticles versus Palladium Acetate as Catalytic Precursors in the Stille Reaction in Water

Published:7 April 2009 DOI: 10.1021/ic9002753 PMID: 19351135
María Bernechea, Ernesto de Jesús*, Carmen López-Mardomingo, Pilar Terreros

Abstract

The performance of several palladium precatalysts, namely, palladium(II) acetate, palladium(0) nanoparticles encapsulated into poly(amidoamine) (PAMAM) dendrimers (Pd DENs), and palladium(II)-PAMAM complexes, in the Stille reaction between trichloro(phenyl)stannane and iodoarenes in water is compared. The reactivity of Pd DENs is similar or inferior to that of palladium(II) acetate, although the presence of the dendrimer suppresses the formation of homocoupling products and allows catalyst recycling. It is suggested that the reaction catalyzed by Pd DENs occurs via palladium species which are leached from the nanoparticle but which remain coordinated to the dendritic macromolecule.

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