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ChemInform Abstract: Reaction of Organometallic Reagents with Ethyl Trifluoroacetate and Diethyl Oxalate. Formation of Trifluoromethyl Ketones and α-Keto Esters via Stable Tetrahedral Adducts.

Published:12 April 1988 DOI: 10.1002/chin.198815157
X. CREARY

Abstract

Reaction of the organometallic reagents (I) with ethyl trifluoroacetate (II) or diethyl oxalate (IV) gives the trifluoromethyl ketones (III) or the α-keto esters (V).

Substances (4)

Related products
Procduct Name CAS Molecular Formula Supplier Price
Ethyl trifluoroacetate 383-63-1 C4H5F3O2 572 suppliers $7.62-$6468.92
Diethyl oxalate 95-92-1 C6H10O4 501 suppliers $5.00-$1000.00
KETONES 4 suppliers Inquiry
α-Keto Isovaleric Acid-13C Sodium Salt 1173023-03-4 C5H7NaO3 1 suppliers Inquiry

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