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      Chemical Safety Data Sheet MSDS / SDS

      2-(5-Norborene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate

      Revision Date:2026-05-31Revision Number:1

      SECTION 1: Identification of the substance/mixture and of the company/undertaking

      Product identifier

      • Product name: 2-(5-Norborene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate
      • CBnumber: CB6697345
      • CAS: 125700-73-4
      • Synonyms: TNTU,2-(5-Norborene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate

      Relevant identified uses of the substance or mixture and uses advised against

      • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
      • Uses advised against: none

      Company Identification

      • Company: Chemicalbook
      • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
      • Telephone: 010-86108875

      SECTION 2: Hazards identification

      GHS Label elements, including precautionary statements

      • Symbol(GHS)
      • Signal wordWarning
      Precautionary statements
      P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
      P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
      P405 Store locked up.
      P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
      Hazard statements
      H315 Causes skin irritation
      H319 Causes serious eye irritation
      H335 May cause respiratory irritation

      SECTION 3: Composition/information on ingredients

      Substance

      • Product name: 2-(5-Norborene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate
      • Synonyms: TNTU,2-(5-Norborene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate
      • CAS: 125700-73-4
      • MF: C14H20BF4N3O3
      • MW: 365.14

      SECTION 4: First aid measures

      General Advice

      If symptoms persist, call a physician.

      Eye Contact

      Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

      Skin Contact

      Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

      Inhalation

      Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

      Ingestion

      Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

      Most important symptoms and effects

      None reasonably foreseeable.

      Self-Protection of the First Aider

      No special precautions required.

      Notes to Physician

      Treat symptomatically.

      SECTION 5: Firefighting measures

      Suitable Extinguishing Media

      Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

      Extinguishing media which must not be used for safety reasons

      No information available.

      Specific Hazards Arising from the Chemical

      Thermal decomposition can lead to release of irritating gases and vapors.

      Protective Equipment and Precautions for Firefighters

      As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

      NFPA 704

      2
      1
      0
      HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
      FIRE 1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
      REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
      SPEC. HAZ.

      SECTION 6: Accidental release measures

      Personal Precautions

      Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.

      Environmental Precautions

      Should not be released into the environment. See Section 12 for additional Ecological Information.

      Methods for Containment and Clean Up

      Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.
      Refer to protective measures listed in Sections 8 and 13.

      SECTION 7: Handling and storage

      Handling

      Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid ingestion and inhalation. Avoid dust formation. Do not get in eyes, on skin, or on clothing.

      Storage

      Keep refrigerated.

      Specific Use(s)

      Use in laboratories

      SECTION 8: Exposure controls/personal protection

      Control Parameters

      Monitoring methods

      BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

      Exposure Controls

      Engineering Measures

      None under normal use conditions. Ensure that eyewash stations and safety showers are close to the workstation location. .

      Personal protective equipment

      Eye Protection
      Goggles (European standard - EN 166)
      Hand Protection
      Protective gloves
      Glove materialBreakthrough timeGlove thicknessEU standardGlove comments
      Nitrile rubberSee manufacturers-EN 374(minimum requirement)
      Neoprenerecommendations
      Natural rubber
      PVC

      Inspect gloves before use.
      Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
      (Refer to manufacturer/supplier for information)
      Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.
      sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion.
      Remove gloves with care avoiding skin contamination.
      Skin and body protection
      Long sleeved clothing
      Respiratory Protection
      No protective equipment is needed under normal use conditions.
      Large scale/emergency use
      Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
      Recommended Filter type: Particle filter
      Small scale/Laboratory use
      Maintain adequate ventilation

      Hygiene Measures

      Handle in accordance with good industrial hygiene and safety practice.

      Environmental exposure controls

      No information available.

      SECTION 9: Physical and chemical properties

      Information on basic physicochemical properties

      • ColourWhite to Almost white
      • Molecular Weight365.13
      • Molecular FormulaC14 H20 BF4 N3 O3
      • Oxidizing PropertiesNo information available
      • Explosive PropertiesNo information available
      • ViscosityNot applicable Solid
      • Decomposition TemperatureNo data available
      • Autoignition TemperatureNo data available
      • Partition Coefficient (n-octanol/water)No data available
      • Solubility in other solventsNo information available
      • Water SolubilitySlightly soluble in water
      • Bulk DensityNo data available
      • Specific Gravity / DensityNo data available
      • Vapor DensityNot applicable Solid
      • Vapor PressureNo data available
      • Explosion LimitsNo data available
      • Flammability (solid,gas)No information available
      • Evaporation RateNot applicable Solid
      • Flash PointNo information available
        Method - No information available
      • Boiling Point/RangeNo information available
      • Softening PointNo data available
      • Melting Point/Range216 - 219 °C / 420.8 - 426.2 °F
      • pHNo information available
      • Odor ThresholdNo data available
      • OdorNo information available
      • Physical StateSolid
      • AppearanceWhite

      SECTION 10: Stability and reactivity

      Stability

      Moisture sensitive. Light sensitive.

      Hazardous Reactions

      None under normal processing.

      Hazardous Polymerization

      No information available.

      Conditions to Avoid

      None known.

      Materials to avoid

      No information available.

      Hazardous Decomposition Products

      Carbon monoxide (CO). Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrogen fluoride.
      Oxides of boron.

      SECTION 11: Toxicological information

      Product Information

      (a) acute toxicity;

      (b) skin corrosion/irritation;

      Category 2

      (c) serious eye damage/irritation;

      Category 2

      (d) respiratory or skin sensitization;

      Respiratory
      No data available
      Skin
      No data available

      (e) germ cell mutagenicity;

      No data available

      (f) carcinogenicity;

      No data available
      There are no known carcinogenic chemicals in this product

      (g) reproductive toxicity;

      No data available

      (h) STOT-single exposure;

      Category 3
      Results / Target organs
      Respiratory system

      (i) STOT-repeated exposure;

      No data available
      Target Organs
      No information available.

      (j) aspiration hazard;

      Not applicable
      Solid

      Symptoms / effects,both acute and delayed

      No information available

      SECTION 12: Ecological information

      Ecotoxicity effects

      Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants.

      Persistence and Degradability

      No information available

      Bioaccumulative Potential

      No information available

      Mobility in soil

      No information available

      Endocrine Disruptor Information

      This product does not contain any known or suspected endocrine disruptors

      Persistent Organic Pollutant

      This product does not contain any known or suspected substance

      Ozone Depletion Potential

      This product does not contain any known or suspected substance

      SECTION 13: Disposal considerations

      Waste from Residues/Unused Products

      Waste is classified as hazardous. Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

      Contaminated Packaging

      Dispose of this container to hazardous or special waste collection point.

      Other Information

      Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains.

      SECTION 14: Transport information

      Road and Rail Transport

      Not Regulated

      IMDG/IMO

      Not regulated

      IATA

      Not regulated

      Special Precautions for User

      No special precautions required

      SECTION 15: Regulatory information

      International Inventories

      X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL).
      ComponentThe Inventory of Hazardous Chemicals(2015 Edition)List of dangerous goods GB 12268-2012TCSIIECSCEINECSTSCADSLPICCSENCSISHLAICSKECL
      O-(5-Norbornene-2,3-d icarboximido)-N,N,N',N '-tetramethyluronium
      BF4
      --X--------

      National Regulations

      SECTION 16: Other information

      Prepared By

      Health, Safety and Environmental Department

      Revision Date

      19-Sep-2025

      Revision Summary

      Not applicable.

      Training Advice

      Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene.

      Legend

      CAS
      Chemical Abstracts Service
      TSCA
      United States Toxic Substances Control Act Section 8(b)
      Inventory
      EINECS/ELINCS
      European Inventory of Existing Commercial Chemical
      Substances/EU List of Notified Chemical Substances
      DSL/NDSL
      Canadian Domestic Substances List/Non-Domestic
      Substances List
      PICCS
      Philippines Inventory of Chemicals and Chemical Substances
      ENCS
      Japanese Existing and New Chemical Substances
      IECSC
      Chinese Inventory of Existing Chemical Substances
      AICS
      Australian Inventory of Chemical Substances
      KECL
      Korean Existing and Evaluated Chemical Substances
      NZIoC
      New Zealand Inventory of Chemicals
      WEL
      Workplace Exposure Limit
      TWA
      Time Weighted Average
      ACGIH
      American Conference of Governmental Industrial Hygienists
      IARC
      International Agency for Research on Cancer
      DNEL
      Derived No Effect Level
      PNEC
      Predicted No Effect Concentration
      RPE
      Respiratory Protective Equipment
      LD50
      Lethal Dose 50%
      LC50
      Lethal Concentration 50%
      EC50
      Effective Concentration 50%
      NOEC
      No Observed Effect Concentration
      POW
      Partition coefficient Octanol:Water
      PBT
      Persistent, Bioaccumulative, Toxic
      vPvB
      very Persistent, very Bioaccumulative
      ICAO/IATA
      International Civil Aviation Organization/International Air
      Transport Association
      IMO/IMDG
      International Maritime Organization/International Maritime
      Dangerous Goods Code
      ADR
      European Agreement Concerning the International Carriage of
      Dangerous Goods by Road
      MARPOL
      International Convention for the Prevention of Pollution from
      Ships
      OECD
      Organisation for Economic Co-operation and Development
      ATE
      Acute Toxicity Estimate
      BCF
      Bioconcentration factor
      VOC
      (Volatile Organic Compound)

      Key literature references and sources for data

      https://echa.europa.eu/information-on-chemicals
      Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

      Disclaimer

      The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
      Disclaimer:

      The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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