Chemical Safety Data Sheet MSDS / SDS
1,4-BUTANEDIOL DIACRYLATE
Revision Date:2026-05-31Revision Number:1
Product identifier
- Product name: 1,4-BUTANEDIOL DIACRYLATE
- CBnumber: CB9262205
- CAS: 1070-70-8
- EINECS Number: 213-979-6
- Synonyms: bdda,1,4-butanediol diacrylate
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
Hazard statements
H412 Harmful to aquatic life with long lasting effects
H317 May cause an allergic skin reaction
H314 Causes severe skin burns and eye damage
H311 Toxic in contact with skin
Substance
- Product name: 1,4-BUTANEDIOL DIACRYLATE
- Synonyms: bdda,1,4-butanediol diacrylate
- CAS: 1070-70-8
- EC number: 213-979-6
- MF: C10H14O4
- MW: 198.22
4.1 Description of first-aid measures
General adviceFirst aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed
Remove contact lenses.
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
4.4 Notes to physician
No data available
5.1 Extinguishing media
Suitable extinguishing mediaWater Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
NFPA 704
3
1
0
| HEALTH | 3 | Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid) | |
| FIRE | 1 | Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb?). Dispose of properly. Clean up affected area.
Chemizorb?). Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditionsTightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage stability
Recommended storage temperature 2 - 8 °C
Storage class
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
8.1 Control parameters
Ingredients with workplace control parametersContains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controlsImmediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: butyl-rubber
Minimum layer thickness: 0.7 mm
Break through time: 480 min
Material tested:Butoject? (KCL 898)
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.4 mm
Break through time: 30 min
Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)
Body Protection
Internet: www.kcl.de).
Full contact
Material: butyl-rubber
Minimum layer thickness: 0.7 mm
Break through time: 480 min
Material tested:Butoject? (KCL 898)
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.4 mm
Break through time: 30 min
Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)
protective clothing
Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Control of environmental exposure
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Do not let product enter drains.
Information on basic physicochemical properties
- a) Physical stateliquid
- b) Colorcolorless
- c) Odorfruity
- d) Melting point/freezing pointMelting point: -6 °C at 1,013.25 hPa - OECD Test Guideline 102
- e) Initial boiling point and boiling range83 °C at 0.4 hPa - lit.
- f) Flammability (solid, gas)No data available
- g) Upper/lower flammability or explosive limitsUpper explosion limit: 7 %(V)
Lower explosion limit: 1.3 %(V) - h) Flash point> 113 °C
- i) Autoignition temperatureNo data available
- j) Decomposition temperatureNo data available
- k) pHNo data available
- l) ViscosityViscosity, kinematic: No data available
Viscosity, dynamic: 4.63 mPa.s at 20 °C - m) Water solubility3.1 g/l at 20 °C - OECD Test Guideline 105
- n) Partition coefficient n-octanol/waterlog Pow: 1.9 at 23 °C - OECD Test Guideline 117 -
Bioaccumulation is not expected. - o) Vapor pressure0.005 hPa at 20 °C - OECD Test Guideline 104
- p) Density1.051 g/mL at 25 °C - lit.
- Relative density1.05 at 20 °C - OECD Test Guideline 109
- r) Particle characteristicsNo data available
- s) Explosive propertiesNo data available
- t) Oxidizing propertiesnone
- Solubility16.3g/l
9.2 Other safety information
No data available
10.1 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.2 Possibility of hazardous reactions
Violent polymerization may be caused by: polymerisation initiators
Strong oxidizing agents strong reducing agents
Peroxides
Strong oxidizing agents strong reducing agents
Peroxides
10.3 Conditions to avoid
Strong heating.
10.4 Incompatible materials
No data available
10.5 Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicityAcute toxicity estimate Oral - 1,337 mg/kg (Calculation method)
LD50 Oral - Rat - male and female - 1,336 mg/kg (OECD Test Guideline 401)
Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor(Calculation method)
LC50 Inhalation - Rat - male and female - 8 h - > 0.06 mg/l - vapor
Remarks: (ECHA)
Acute toxicity estimate Dermal - 300 mg/kg (Calculation method)
LD50 Dermal - Rat - male and female - 400 - 800 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation
LD50 Oral - Rat - male and female - 1,336 mg/kg (OECD Test Guideline 401)
Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor(Calculation method)
LC50 Inhalation - Rat - male and female - 8 h - > 0.06 mg/l - vapor
Remarks: (ECHA)
Acute toxicity estimate Dermal - 300 mg/kg (Calculation method)
LD50 Dermal - Rat - male and female - 400 - 800 mg/kg (OECD Test Guideline 402)
Remarks: Causes skin burns.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Serious eye damage/eye irritation
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Eyes - Rabbit
Result: Causes serious eye damage.
(OECD Test Guideline 405)
Remarks: Causes serious eye damage.
Respiratory or skin sensitization
Result: Causes serious eye damage.
(OECD Test Guideline 405)
Remarks: Causes serious eye damage.
Local lymph node assay (LLNA) - Mouse
Result: positive (OECD Test Guideline 429)
Germ cell mutagenicity
Result: positive (OECD Test Guideline 429)
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: Micronucleus test
Test system: human lymphoblastoid cells
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 487
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: Micronucleus test
Species: Mouse
Cell type: Bone marrow
Application Route: Oral
Method: OECD Test Guideline 474
Result: negative
Carcinogenicity
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: Micronucleus test
Test system: human lymphoblastoid cells
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 487
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: Micronucleus test
Species: Mouse
Cell type: Bone marrow
Application Route: Oral
Method: OECD Test Guideline 474
Result: negative
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
11.2 Additional Information
Repeated dose toxicity - Rat - male and female - Oral - NOAEL (No observed adverse effect level) - 200 mg/kg burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Handle in accordance with good industrial hygiene and safety practice.
Handle in accordance with good industrial hygiene and safety practice.
12.1 Toxicity
Toxicity to fish static test LC50 - Danio rerio (zebra fish) - 1.0 - 2.15 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 4.59 mg/l - 48 h and other aquatic (Regulation (EC) No. 440/2008, Annex, C.2) invertebrates
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 1.76 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - Pseudomonas putida - 5,650 mg/l - 16 h (ISO 10712)
Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 4.59 mg/l - 48 h and other aquatic (Regulation (EC) No. 440/2008, Annex, C.2) invertebrates
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 1.76 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - Pseudomonas putida - 5,650 mg/l - 16 h (ISO 10712)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 22 d
Result: 90 - 100 % - Readily biodegradable.
Remarks: (ECHA)
Result: 90 - 100 % - Readily biodegradable.
Remarks: (ECHA)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
Discharge into the environment must be avoided.
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Offer surplus and non-recyclable solutions to a licensed disposal company.
14.1 UN number
ADR/RID: 2922
IMDG: 2922
IATA-DGR: 2922
IMDG: 2922
IATA-DGR: 2922
14.2 UN proper shipping name
ADR/RID: CORROSIVE LIQUID, TOXIC, N.O.S. (1,4-butyleneglycol diacrylate) (1,4- butyleneglycol diacrylate)
IMDG: CORROSIVE LIQUID, TOXIC, N.O.S. (1,4-butyleneglycol diacrylate) (1,4- butyleneglycol diacrylate)
IATA-DGR: Corrosive liquid, toxic, n.o.s. (1,4-butyleneglycol diacrylate) (1,4- butyleneglycol diacrylate)
IMDG: CORROSIVE LIQUID, TOXIC, N.O.S. (1,4-butyleneglycol diacrylate) (1,4- butyleneglycol diacrylate)
IATA-DGR: Corrosive liquid, toxic, n.o.s. (1,4-butyleneglycol diacrylate) (1,4- butyleneglycol diacrylate)
14.3 Transport hazard class(es)
ADR/RID: 8 (6.1)
IMDG: 8 (6.1)
IATA-DGR: 8 (6.1)
IMDG: 8 (6.1)
IATA-DGR: 8 (6.1)
14.4 Packaging group
ADR/RID: II
IMDG: II
IATA-DGR: II
IMDG: II
IATA-DGR: II
14.5 Environmental hazards
ADR/RID: no
IMDG Marine pollutant: no
IATA-DGR: no
IMDG Marine pollutant: no
IATA-DGR: no
14.6 Special precautions for user
Based on chemical properties, choose appropriate tools and conditions of transport.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
14.7 Incompatible materials
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.
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