Chemical Safety Data Sheet MSDS / SDS
TRICHLOROETHYLENE-D
Revision Date:2026-05-31Revision Number:1
Product identifier
- Product name: TRICHLOROETHYLENE-D
- CBnumber: CB7747467
- CAS: 13291-68-4
- Synonyms: Trichloroethylene-d
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
Hazard statements
H315 Causes skin irritation
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
H341 Suspected of causing genetic defects
H350 May cause cancer
H412 Harmful to aquatic life with long lasting effects
Substance
- Product name: TRICHLOROETHYLENE-D
- Synonyms: Trichloroethylene-d
- CAS: 13291-68-4
- MF: C2Cl3D
- MW: 132.39
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Protection of first-aiders
For personal protection see section 8.
Notes to physician
No data available
Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
Specific hazards during fire fighting
Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.
Hazardous combustion products
Carbon oxides Hydrogen chloride gas
Specific extinguishing methods
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Special protective equipment for fire-fighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material . Dispose of properly. Clean up affected area.
Handling
Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Storage
Further information on storage conditionsTightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage class
6.1C, Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
Recommended storage temperature
Recommended storage temperature see product label.
Ingredients with workplace control parameters
Biological occupational exposure limits the week
Engineering measures
No data available
Personal protective equipment
Respiratory protectionrequired when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Filter A (acc. to DIN 3181) for vapours of organic
type
compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Eye/face protection
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Safety glasses
Skin and body protection
Safety glasses
protective clothing
Hand protection
Material
Viton?
Break through time
480 min
Glove thickness
0.7 mm
Protective index
Full contact
Manufacturer
Vitoject? (KCL 890 / Aldrich Z677698, Size M)
Material
Nitrile rubber
Break through time
10 min
Glove thickness
0.4 mm
Protective index
Splash contact
Manufacturer
Camatril? (KCL 730 / Aldrich Z677442, Size M)
Remarks
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D- 36124 Eichenzell, Internet: www.kcl.de).
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Information on basic physicochemical properties
- SolubilityChloroform (Slightly), Methanol (Slightly)
- Physical stateOil
- Appearanceclear, liquid
- Colorcolorless
- OdorNo data available
- Odor ThresholdNo data available
- pHNo data available
- Melting point/ range-84.8 °C
- Boiling point/boiling range86.7 °C
- Flash pointNo data available
- Evaporation rateNo data available
- Flammability (solid, gas)No data available
- Flammability (liquids)No data available
- Burning rateNo data available
- Upper explosion limit / Upper flammability limitNo data available
- Lower explosion limit / Lower flammability limitNo data available
- Vapor pressureNo data available
- Relative vapor densityNo data available
- Relative density1.474 g/mL at 25 °C
- Density1.474 g/mL (25 °C) 1.474 g/cm3 (25 °C)
- Water solubilityNo data available
- Partition coefficient: n-octanol/waterNo data available
- Autoignition temperatureNo data available
- Decomposition temperatureNo data available
- Viscosity, dynamicNo data available
- Viscosity, kinematicNo data available
- Flow timeNo data available
- Explosive propertiesNo data available
- Oxidizing propertiesnone
- Molecular weight132.40 g/mol
- Particle characteristics Particle sizeNo data available
Reactivity
No data available
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Violent reactions possible with: Oxygen (as liquefied gas) Alkaline earth metals alkali amides semimetallic hydrogen compounds perchloric acid Light metals aluminium chloride Strong oxidizing agents potassium nitrate Risk of explosion with: Alkali metals Aluminum Barium alkali hydroxides Lithium magnesium Powdered metals sodium amide Strong oxidizing agents nitrogen dioxide Boranes Oxygen with alkali hydroxides Oxygen with Pressure Risk of ignition or formation of inflammable gases or vapours with: Titanium Beryllium Epoxy constituents
Conditions to avoid
no information available
Incompatible materials
No data available
Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicityOral: No data available
LC50 Inhalation - Rat - male - 4 h - 67.41 mg/l
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
LD50 Dermal - Rabbit - > 20,000 mg/kg
Remarks: (RTECS)
The value is given in analogy to the following substances: trichloroethylene
Skin corrosion/irritation
LC50 Inhalation - Rat - male - 4 h - 67.41 mg/l
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
LD50 Dermal - Rabbit - > 20,000 mg/kg
Remarks: (RTECS)
The value is given in analogy to the following substances: trichloroethylene
Skin - Rabbit
Result: Skin irritation - 4 h (OECD Test Guideline 404)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Remarks: Drying-out effect resulting in rough and chapped skin.
Serious eye damage/eye irritation
Result: Skin irritation - 4 h (OECD Test Guideline 404)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Remarks: Drying-out effect resulting in rough and chapped skin.
Eyes - Rabbit
Result: Eye irritation - 24 h
Remarks: (RTECS)
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Respiratory or skin sensitization
Result: Eye irritation - 24 h
Remarks: (RTECS)
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Local lymph node assay (LLNA) - Mouse
Result: positive (OECD Test Guideline 429)
Remarks: The value is given in analogy to the following substances: trichloroeth- ylene
Germ cell mutagenicity
Result: positive (OECD Test Guideline 429)
Remarks: The value is given in analogy to the following substances: trichloroeth- ylene
Suspected of causing genetic defects.
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 471
Result: negative
Remarks: The value is given in analogy to the following substances: trichloroeth- yleneTest Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Remarks: The value is given in analogy to the following substances: trichloroeth- yleneTest Type: Chromosome aberration test in vitro
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Result: negative
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
Test Type: in vivo assay
Species: Mouse
Result: negative
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
Carcinogenicity
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 471
Result: negative
Remarks: The value is given in analogy to the following substances: trichloroeth- yleneTest Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Remarks: The value is given in analogy to the following substances: trichloroeth- yleneTest Type: Chromosome aberration test in vitro
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Result: negative
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
Test Type: in vivo assay
Species: Mouse
Result: negative
Remarks: (ECHA)
The value is given in analogy to the following substances: trichloroethylene
Presumed to have carcinogenic potential for humans
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness. - Central nervous system
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Specific target organ toxicity - repeated exposure
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: trichloroethylene
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
11.2 Additional Information
burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache,
Nausea, Vomiting, Exposure to and/or consumption of alcohol may increase toxic effects., Gastrointestinal disturbance, Kidney injury may occur., narcosis
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Nausea, Vomiting, Exposure to and/or consumption of alcohol may increase toxic effects., Gastrointestinal disturbance, Kidney injury may occur., narcosis
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Ecotoxicity
Components:
Trichloroethylene-d:
Toxicity to fishLC50 (Jordanella floridae): 28.3 mg/l End point: mortality Exposure time: 96 h Test Type: flow-through test Analytical monitoring: yes Method: US-EPA Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Toxicity to algae/aquatic plants
ErC50 (Chlamydomonas reinhardtii (green algae)): 36.5 mg/l Exposure time: 72 h Analytical monitoring: yes Remarks: (ECHA) The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Toxicity to fish (Chronic toxicity)
NOEC (Jordanella floridae (flagfish)): 5.76 mg/l End point: mortality Exposure time: 10 d Test Type: flow-through test Analytical monitoring: yes Remarks: (ECHA) The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Toxicity to microorganisms
EC50 (activated sludge): 260 mg/l Exposure time: 3 h Test Type: static test Method: OECD Test Guideline 209 Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Persistence and degradability
Components:
Trichloroethylene-d:
Biodegradabilityaerobic Inoculum: activated sludge Result: Not readily biodegradable. Biodegradation: 19 % Exposure time: 28 d Method: OECD Test Guideline 301D Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Bioaccumulative potential
Components:
Trichloroethylene-d:
BioaccumulationSpecies: Lepomis macrochirus Bioconcentration factor (BCF): 17 Exposure time: 14 d Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: trichloroethylene
Mobility in soil
No data available
Other adverse effects
No data available
Disposal methods
Waste from residuesOffer surplus and non-recyclable solutions to a licensed disposal company.
International Regulations
IATA-DGR
UN/ID No. : UN 1710
Proper shipping name : Trichloroethylene
Class : 6.1
Packing group : III
Labels : Division 6.1 - Toxic substances
Packing instruction (cargo aircraft) : 663
Packing instruction (passenger aircraft) : 655
Proper shipping name : Trichloroethylene
Class : 6.1
Packing group : III
Labels : Division 6.1 - Toxic substances
Packing instruction (cargo aircraft) : 663
Packing instruction (passenger aircraft) : 655
IMDG-Code
UN number : UN 1710
Proper shipping name : TRICHLOROETHYLENE
Class : 6.1
Packing group : III
Labels : 6.1
EmS Code : F-A, S-A
Marine pollutant : no
Proper shipping name : TRICHLOROETHYLENE
Class : 6.1
Packing group : III
Labels : 6.1
EmS Code : F-A, S-A
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National regulation GB 6944/12268
UN number : UN 1710
Proper shipping name : TRICHLOROETHYLENE
Class : 6.1
Packing group : III
Labels : 6.1
National regulation GB 6944/12268
UN number : UN 1710
Proper shipping name : TRICHLOROETHYLENE
Class : 6.1
Packing group : III
Labels : 6.1
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
National regulatory information
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals
Identification of Major Hazard Installations for Hazardous Chemicals (GB 18218)
Not listed
Hazardous Chemicals for Priority Management
Not listed under SAWS
Regulations on Occupational Labor Protection in the at workplaces where
Toxic Substances Are Used
Catalogue of Highly Toxic Chemicals
Not listed
Regulation of Environmental Management on the First Import of Chemicals and the Import and Export of Toxic Chemicals
China Severely Restricted Toxic Chemicals for Import and Export
Not listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number
B1A222232820
Full text of other abbreviations
ACGIHUSA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI
ACGIH - Biological Exposure Indices (BEI)
CN BEI
China. Biological Occupational Exposure Indices
GBZ 2.1-2007
Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents.
ACGIH / TWA
8-hour, time-weighted average
ACGIH / STEL
Short-term exposure limit
GBZ 2.1-2007 / PC-TWA AIIC - Australian Invent Transport by Land of Bra bw - Body weight; CMR Standard of the German List (Canada); ECx - Conc associated with x% respo Chemical Substances (Jap response; ERG - Emerge GLP - Good Laboratory P cer; IATA - International Construction and Equipm Half maximal inhibitory c tion; IECSC - Inventory o tional Maritime Dangerou Industrial Safety and H Standardization; KECI - K tration to 50 % of a test (Median Lethal Dose); MA lution from Ships; n.o.s. No Observed (Adverse) E fect Level; NOELR - No Norm; NTP - National Toxi icals; OECD - Organizatio fice of Chemical Safety a and Toxic substance; PIC stances; (Q)SAR - (Quant (EC) No 1907/2006 of th Registration, Evaluation, Accelerating Decompositi Chemical Substance Inve Thailand Existing Chemica States); UN - United Nat Transport of Dangerous WHMIS - Workplace Hazar
Permissible concentration - time weighted average ry of Industrial Chemicals
ANTT - National Agency for il
ASTM - American Society for the Testing of Materials
- Carcinogen, Mutagen or Reproductive Toxicant
DIN nstitute for Standardisation
DSL - Domestic Substances ntration associated with x% response
ELx - Loading rate se
EmS - Emergency Schedule
ENCS - Existing and New n)
ErCx - Concentration associated with x% growth rate cy Response Guide
GHS - Globally Harmonized System
actice
IARC - International Agency for Research on Canir Transport Association
IBC - International Code for the nt of Ships carrying Dangerous Chemicals in Bulk
IC50 ncentration
ICAO - International Civil Aviation Organiza- Existing Chemical Substances in China
IMDG - Interna- Goods
IMO - International Maritime Organization
ISHL alth Law (Japan)
ISO - International Organisation for rea Existing Chemicals Inventory
LC50 - Lethal Concenopulation
LD50 - Lethal Dose to 50% of a test population POL - International Convention for the Prevention of Pol- Not Otherwise Specified
Nch - Chilean Norm
NO(A)EC fect Concentration
NO(A)EL - No Observed (Adverse) Efbservable Effect Loading Rate
NOM - Official Mexican ology Program
NZIoC - New Zealand Inventory of Chemfor Economic Co-operation and Development
OPPTS - Ofd Pollution Prevention
PBT - Persistent, Bioaccumulative S - Philippines Inventory of Chemicals and Chemical Subtative) Structure Activity Relationship
REACH - Regulation European Parliament and of the Council concerning the uthorisation and Restriction of Chemicals
SADT - Selfn Temperature
SDS - Safety Data Sheet
TCSI - Taiwan tory
TDG - Transportation of Dangerous Goods
TECI s Inventory
TSCA - Toxic Substances Control Act (United ons
UNRTDG - United Nations Recommendations on the oods
vPvB - Very Persistent and Very Bioaccumulative
ous Materials Information System
ANTT - National Agency for il
ASTM - American Society for the Testing of Materials
- Carcinogen, Mutagen or Reproductive Toxicant
DIN nstitute for Standardisation
DSL - Domestic Substances ntration associated with x% response
ELx - Loading rate se
EmS - Emergency Schedule
ENCS - Existing and New n)
ErCx - Concentration associated with x% growth rate cy Response Guide
GHS - Globally Harmonized System
actice
IARC - International Agency for Research on Canir Transport Association
IBC - International Code for the nt of Ships carrying Dangerous Chemicals in Bulk
IC50 ncentration
ICAO - International Civil Aviation Organiza- Existing Chemical Substances in China
IMDG - Interna- Goods
IMO - International Maritime Organization
ISHL alth Law (Japan)
ISO - International Organisation for rea Existing Chemicals Inventory
LC50 - Lethal Concenopulation
LD50 - Lethal Dose to 50% of a test population POL - International Convention for the Prevention of Pol- Not Otherwise Specified
Nch - Chilean Norm
NO(A)EC fect Concentration
NO(A)EL - No Observed (Adverse) Efbservable Effect Loading Rate
NOM - Official Mexican ology Program
NZIoC - New Zealand Inventory of Chemfor Economic Co-operation and Development
OPPTS - Ofd Pollution Prevention
PBT - Persistent, Bioaccumulative S - Philippines Inventory of Chemicals and Chemical Subtative) Structure Activity Relationship
REACH - Regulation European Parliament and of the Council concerning the uthorisation and Restriction of Chemicals
SADT - Selfn Temperature
SDS - Safety Data Sheet
TCSI - Taiwan tory
TDG - Transportation of Dangerous Goods
TECI s Inventory
TSCA - Toxic Substances Control Act (United ons
UNRTDG - United Nations Recommendations on the oods
vPvB - Very Persistent and Very Bioaccumulative
ous Materials Information System
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.