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ChemicalBook >> CAS DataBase List >> (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL price.
  • $12 - $1815
  • Product name: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
  • CAS: 100165-88-6
  • MF: C48H40P2
  • MW: 678.78
  • EINECS:1312995-182-4
  • MDL Number:MFCD00269856
  • Synonyms:(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL;(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-&;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98+%;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%(S)-Tol-BINAP;(S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-1,1''-BINAPHTHYL (S)-TOL-BINAP;(S)-(-)-2,2''-Bis-[bis-(p-tolylphosphino)]-1,1''-binaphthyl;PHOSPHINE, 1,1''-(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[1,1-BIS(4-METHYLPHENYL)-;(S)-T-BINAP
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  • Manufactureraablocks
  • Product numberAA00H93K
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl ≥98%
  • Packaging250mg
  • Price$12
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00H93K
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98%
  • Packaging1g
  • Price$26
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00H93K
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98%
  • Packaging10g
  • Price$219
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA00H93K
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98%
  • Packaging5g
  • Price$113
  • Updated2026-05-28
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  • ManufacturerACHEMBLOCK
  • Product numberX208920
  • Product description(R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97%
  • Packaging100G
  • Price$1815
  • Updated2026-05-27
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  • ManufacturerACHEMBLOCK
  • Product numberX208920
  • Product description(R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97%
  • Packaging25G
  • Price$605
  • Updated2026-05-27
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  • ManufacturerACHEMBLOCK
  • Product numberX208920
  • Product description(R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97%
  • Packaging5G
  • Price$135
  • Updated2026-05-27
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  • ManufacturerAK Scientific
  • Product number7122AC
  • Product description(S)-T-BINAP
  • Packaging1g
  • Price$147
  • Updated2021-12-16
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  • ManufacturerAlichem
  • Product number100165886
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
  • Packaging5g
  • Price$424.2
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA491448
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+%
  • Packaging25g
  • Price$678
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA491448
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+%
  • Packaging5g
  • Price$148
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA491448
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+%
  • Packaging10g
  • Price$281
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA491448
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+%
  • Packaging1g
  • Price$35
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA491448
  • Product description(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+%
  • Packaging250mg
  • Price$14
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY059147
  • Product description(S)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene >98%
  • Packaging1g
  • Price$19
  • Updated2026-05-26
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  • ManufacturerArctom
  • Product numberSY059147
  • Product description(S)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene >98%
  • Packaging0.25g
  • Price$13
  • Updated2026-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA00H93K (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl ≥98% 250mg $12 2026-05-28 Buy
aablocks AA00H93K (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98% 1g $26 2026-05-28 Buy
aablocks AA00H93K (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98% 10g $219 2026-05-28 Buy
aablocks AA00H93K (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98% 5g $113 2026-05-28 Buy
ACHEMBLOCK X208920 (R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97% 100G $1815 2026-05-27 Buy
ACHEMBLOCK X208920 (R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97% 25G $605 2026-05-27 Buy
ACHEMBLOCK X208920 (R)-2,2'-bis(di-p-tolylphosphaneyl)-1,1'-binaphthalene 97% 5G $135 2026-05-27 Buy
AK Scientific 7122AC (S)-T-BINAP 1g $147 2021-12-16 Buy
Alichem 100165886 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 5g $424.2 2021-12-16 Buy
Ambeed A491448 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+% 25g $678 2021-12-16 Buy
Ambeed A491448 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+% 5g $148 2021-12-16 Buy
Ambeed A491448 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+% 10g $281 2021-12-16 Buy
Ambeed A491448 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+% 1g $35 2021-12-16 Buy
Ambeed A491448 (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 98+% 250mg $14 2021-12-16 Buy
Arctom SY059147 (S)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene >98% 1g $19 2026-05-26 Buy
Arctom SY059147 (S)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene >98% 0.25g $13 2026-05-26 Buy

Properties

Melting point :252-256 °C
alpha :-160° (c 0.5, C6H6)
Boiling point :754.4±60.0 °C(Predicted)
storage temp. :Inert atmosphere,Room Temperature
form :Powder
color :White
optical activity :[α]20/D -156°, c = 0.5 in benzene
Water Solubility :Insoluble in water.
InChIKey :IOPQYDKQISFMJI-UHFFFAOYSA-N
SMILES :P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1
CAS DataBase Reference :100165-88-6(CAS DataBase Reference)

Safety Information

Symbol(GHS): Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium

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