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ChemicalBook >> CAS DataBase List >> CHLOROMETHYLDIMETHYLPHENYLSILANE

CHLOROMETHYLDIMETHYLPHENYLSILANE

CHLOROMETHYLDIMETHYLPHENYLSILANE price.
  • $8 - $1248
  • Product name: CHLOROMETHYLDIMETHYLPHENYLSILANE
  • CAS: 1833-51-8
  • MF: C9H13ClSi
  • MW: 184.74
  • EINECS:217-392-6
  • MDL Number:MFCD00040858
  • Synonyms:(chloromethyl)dimethylphenyl-silan ;Dichloromethyldimethylphenylsilane;Phenyldimethyl(chloromethyl)silane;CHLOROMETHYLDIMETHYLPHENYLSILANE;Silane, (chloromethyl)dimethylphenyl-;Dimethylphenylsilyldichloromethane;Chloromethylphenyldimethylsilane;Phenyl(chloromethyl)dimethylsilane
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  • Manufactureraablocks
  • Product numberAA0027ES
  • Product description(chloromethyl)dimethylphenylsilane 97%
  • Packaging25g
  • Price$61
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA0027ES
  • Product description(chloromethyl)dimethylphenylsilane 97%
  • Packaging5g
  • Price$15
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA0027ES
  • Product description(chloromethyl)dimethylphenylsilane 97%
  • Packaging1g
  • Price$10
  • Updated2026-05-28
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  • Manufactureraablocks
  • Product numberAA0027ES
  • Product description(chloromethyl)dimethylphenylsilane 97%
  • Packaging250mg
  • Price$8
  • Updated2026-05-28
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  • ManufacturerACHEMBLOCK
  • Product numberW162788
  • Product description(Chloromethyl)dimethyl(phenyl)silane 98%
  • Packaging100G
  • Price$170
  • Updated2026-05-27
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  • ManufacturerAK Scientific
  • Product number9605AA
  • Product description(Chloromethyl)dimethyl(phenyl)silane
  • Packaging5g
  • Price$120
  • Updated2021-12-16
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  • Product number9605AA
  • Product description(Chloromethyl)dimethyl(phenyl)silane
  • Packaging25g
  • Price$259
  • Updated2021-12-16
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  • Product numberA985316
  • Product description(Chloromethyl)dimethyl(phenyl)silane 97%
  • Packaging100g
  • Price$454
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  • Product description(Chloromethyl)dimethyl(phenyl)silane 97%
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  • Product numberA985316
  • Product description(Chloromethyl)dimethyl(phenyl)silane 97%
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  • Product description(Chloromethyl)dimethyl(phenyl)silane 97%
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  • Product description(Chloromethyl)dimethyl(phenyl)silane 97%
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  • Product numberOR933157
  • Product description(Chloromethyl)(dimethyl)phenylsilane 97%
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  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberOR933157
  • Product description(Chloromethyl)(dimethyl)phenylsilane 97%
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  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberOR933157
  • Product description(Chloromethyl)(dimethyl)phenylsilane 97%
  • Packaging25g
  • Price$51
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberOR933157
  • Product description(Chloromethyl)(dimethyl)phenylsilane 97%
  • Packaging25g
  • Price$51
  • Updated2026-06-04
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Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA0027ES (chloromethyl)dimethylphenylsilane 97% 25g $61 2026-05-28 Buy
aablocks AA0027ES (chloromethyl)dimethylphenylsilane 97% 5g $15 2026-05-28 Buy
aablocks AA0027ES (chloromethyl)dimethylphenylsilane 97% 1g $10 2026-05-28 Buy
aablocks AA0027ES (chloromethyl)dimethylphenylsilane 97% 250mg $8 2026-05-28 Buy
ACHEMBLOCK W162788 (Chloromethyl)dimethyl(phenyl)silane 98% 100G $170 2026-05-27 Buy
AK Scientific 9605AA (Chloromethyl)dimethyl(phenyl)silane 5g $120 2021-12-16 Buy
AK Scientific 9605AA (Chloromethyl)dimethyl(phenyl)silane 25g $259 2021-12-16 Buy
Ambeed A985316 (Chloromethyl)dimethyl(phenyl)silane 97% 100g $454 2021-12-16 Buy
Ambeed A985316 (Chloromethyl)dimethyl(phenyl)silane 97% 1g $22 2021-12-16 Buy
Ambeed A985316 (Chloromethyl)dimethyl(phenyl)silane 97% 25g $145 2021-12-16 Buy
Ambeed A985316 (Chloromethyl)dimethyl(phenyl)silane 97% 5g $36 2021-12-16 Buy
Ambeed A985316 (Chloromethyl)dimethyl(phenyl)silane 97% 250mg $9 2021-12-16 Buy
Apolloscientific OR933157 (Chloromethyl)(dimethyl)phenylsilane 97% 500g $803 2026-06-04 Buy
Apolloscientific OR933157 (Chloromethyl)(dimethyl)phenylsilane 97% 500g $803 2026-06-04 Buy
Apolloscientific OR933157 (Chloromethyl)(dimethyl)phenylsilane 97% 25g $51 2026-06-04 Buy
Apolloscientific OR933157 (Chloromethyl)(dimethyl)phenylsilane 97% 25g $51 2026-06-04 Buy

Properties

Boiling point :106-107 °C/15 mmHg (lit.)
Density :1.024 g/mL at 25 °C (lit.)
refractive index :n20/D 1.520(lit.)
Flash point :196 °F
storage temp. :2-8°C
form :clear liquid
color :Colorless to Almost colorless
Specific Gravity :1.031
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
BRN :2935991
InChI :1S/C9H13ClSi/c1-11(2,8-10)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
InChIKey :RJCTVFQQNCNBHG-UHFFFAOYSA-N
SMILES :C[Si](C)(CCl)c1ccccc1
CAS DataBase Reference :1833-51-8(CAS DataBase Reference)
EPA Substance Registry System :Silane, (chloromethyl)dimethylphenyl- (1833-51-8)

Safety Information

Symbol(GHS): Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

The first reported preparation and use of (chloromethyl)dimethylphenylsilane was in 1949.At the time, the main utility of (chloromethyl)dimethylphenylsilane was as the starting material for conversion to the corresponding Grignard reagent (see below). Since then, it has also been used for heteroatom alkylation, carbon alkylation, and conversion to a variety of organometallic and organolanthanide reagents. The main advantage of this reagent over the closely related (chloromethyl)trimethylsilane is the ability of (chloromethyl)dimethylphenylsilane to undergo a Fleming oxidation, thus allowing (chloromethyl)dimethylphenylsilane to serve as a masked hydroxyl group. This utility has been exploited for both the C-substituted and Nsubstituted adducts. A major disadvantage of the use of (chloromethyl)dimethylphenylsilane is its propensity to undergo rearrangements under a variety of conditions (see below). (Chloromethyl) dimethylphenylsilane is used as the precursor for the preparation of (phenyldimethylsilyl)methoxymethyl chloride (SMOM-Cl), a hydroxyl protecting group.
(Chloromethyl)dimethylphenylsilane (1) can be utilized to install a silylmethyl group on carbon via base promoted C-alkylation of terminal alkynes,dihydropyrazines,malonic esters,phenylacetonitriles,sulfoxides,and imines.Although has been used directly in the alkylation, conversion to the corresponding iodide via Finkelstein displacement (eq 1) prior to alkylation is sometimeswarranted. Except for the malonic esters (eq 2), strongly basic conditions and lowtemperatures (with slow warming) are generally employed in the transformation (eqs 3 and 4).	CHLOROMETHYLDIMETHYLPHENYLSILANE

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