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ChemicalBook >> CAS DataBase List >> 3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE price.
  • $12 - $4120
  • Product name: 3-BROMOCYCLOHEXENE
  • CAS: 1521-51-3
  • MF: C6H9Br
  • MW: 161.04
  • EINECS:
  • MDL Number:MFCD00013775
  • Synonyms:1-Bromo-2-cyclohexene;2-Cyclohexenyl bromide;1,2,3,4-TETRAHYDROBROMOBENZENE;2-CYCLOHEXEN-1-YL BROMIDE;(+/-)-3-BROMOCYCLOHEXENE;3-BROMOCYCLOHEXENE;TIMTEC-BB SBB007864;3-BROMOCYCLOHEXENE, TECH., 90%
25 prices
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Brand
  • aablocks
  • AccelPharmtech
  • ACHEMBLOCK
  • AK Scientific
  • Matrix Scientific
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
  • Thermo Scientific Chemicals
  • TRC
Package
  • 1g
  • 5.00g
  • 5g
  • 5mL
  • 10ml
  • 10g
  • 20g
  • 25mL
  • 25g
  • 25.00g
  • 50ml
  • 100G
  • 250ml
  • 2KG
  • 10 mL
  • Manufactureraablocks
  • Product numberAA0039JX
  • Product description3-Bromocyclohexene 95%
  • Packaging20g
  • Price$50
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA0039JX
  • Product description3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide
  • Packaging25g
  • Price$52
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA0039JX
  • Product description3-Bromocyclohexene 95%
  • Packaging10g
  • Price$39
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA0039JX
  • Product description3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide
  • Packaging1g
  • Price$12
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA0039JX
  • Product description3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide
  • Packaging5g
  • Price$31
  • Updated2026-05-28
  • Buy
  • ManufacturerAccelPharmtech
  • Product numberLP1221
  • Product description3-bromocyclohexene 95%
  • Packaging2KG
  • Price$4120
  • Updated2026-05-21
  • Buy
  • ManufacturerACHEMBLOCK
  • Product numberP44668
  • Product description3-bromocyclohex-1-ene 97%
  • Packaging100G
  • Price$320
  • Updated2026-05-27
  • Buy
  • ManufacturerAK Scientific
  • Product numberR943
  • Product description3-Bromocyclohexene
  • Packaging1g
  • Price$69
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene 95+%
  • Packaging5g
  • Price$35
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene 95+%
  • Packaging100g
  • Price$449
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene
  • Packaging5.00g
  • Price$42
  • Updated2026-05-18
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene
  • Packaging25.00g
  • Price$74
  • Updated2026-05-18
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging5g
  • Price$39
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging25g
  • Price$160
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging1g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging250ml
  • Price$1690
  • Updated2026-04-30
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA0039JX 3-Bromocyclohexene 95% 20g $50 2026-05-28 Buy
aablocks AA0039JX 3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide 25g $52 2026-05-28 Buy
aablocks AA0039JX 3-Bromocyclohexene 95% 10g $39 2026-05-28 Buy
aablocks AA0039JX 3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide 1g $12 2026-05-28 Buy
aablocks AA0039JX 3-Bromocyclohexene 97%stab.with300-1000ppmPropyleneoxide 5g $31 2026-05-28 Buy
AccelPharmtech LP1221 3-bromocyclohexene 95% 2KG $4120 2026-05-21 Buy
ACHEMBLOCK P44668 3-bromocyclohex-1-ene 97% 100G $320 2026-05-27 Buy
AK Scientific R943 3-Bromocyclohexene 1g $69 2021-12-16 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 95+% 5g $35 2021-12-16 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 95+% 100g $449 2021-12-16 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 5.00g $42 2026-05-18 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 25.00g $74 2026-05-18 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 5g $39 2021-12-16 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 25g $160 2021-12-16 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 1g $14 2021-12-16 Buy
Sigma-Aldrich 333549 3-Bromocyclohexene technical grade, 90% 250ml $1690 2026-04-30 Buy

Properties

Melting point :131-134 °C
Boiling point :57-58 °C/12 mmHg (lit.)
Density :1.4 g/mL at 25 °C (lit.)
refractive index :n20/D 1.528(lit.)
Flash point :130 °F
storage temp. :-20°C
form :Solid
color :White to off-white
Water Solubility :Not miscible or difficult to mix in water.
BRN :635953
InChI :InChI=1S/C6H9Br/c7-6-4-2-1-3-5-6/h2,4,6H,1,3,5H2
InChIKey :AJKDUJRRWLQXHM-UHFFFAOYSA-N
SMILES :C1CCCC(Br)C=1
CAS DataBase Reference :1521-51-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): Flame (GHS02)Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger. It is also used in the synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine.1 It was also used in the synthesis of enantiopure cyclohexitols such as muco-quercitol, D-chiro-inocitol and allo-inocitol.

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