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ChemicalBook >> CAS DataBase List >> Hypophosphorous acid

Hypophosphorous acid

Hypophosphorous acid price.
  • $10.16 - $4304.54
  • Product name: Hypophosphorous acid
  • CAS: 6303-21-5
  • MF: HO2P
  • MW: 63.980501
  • EINECS:228-601-5
  • MDL Number:MFCD02183592
  • Synonyms:Diphosphoric(IV) acid;Hypophosphorous acid, 50 wt.% solution in water 1LT;Hypophosphorous acid (HPA);Hypophosphorous acid, 50 wt.% solution in H2O;Hypophosphorous Acid, 30 Percent (w/v) Solution;Hypophosphorous acid aqueous solution;Hypophosphorous Acid 50%/70% (HPA);Hypophosphorous acid solution 50 wt. % in H2O
25 prices
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  • American Custom Chemicals Corporation
  • Atlantic Research Chemicals
  • GFS CHEMICALS
  • Sigma-Aldrich
  • Thermo Scientific Chemicals
  • Usbiological
Package
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  • *4x500g
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  • 4x4kg
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004334
  • Product descriptionHYPOPHOSPHOROUS ACID 95.00%
  • Packaging50G
  • Price$2460.42
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004334
  • Product descriptionHYPOPHOSPHOROUS ACID 95.00%
  • Packaging500G
  • Price$4304.54
  • Updated2021-12-16
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002398
  • Product descriptionHypophosphorous acid (50% w/w aq sol) 95
  • Packaging1g
  • Price$10.16
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002400
  • Product descriptionHypophosphorous acid 95
  • Packaging1g
  • Price$10.16
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002398
  • Product descriptionHypophosphorous acid (50% w/w aq sol) 95
  • Packaging5g
  • Price$15.24
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002400
  • Product descriptionHypophosphorous acid 95
  • Packaging5g
  • Price$15.24
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002398
  • Product descriptionHypophosphorous acid (50% w/w aq sol) 95
  • Packaging10g
  • Price$17.78
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002398
  • Product descriptionHypophosphorous acid (50% w/w aq sol) 95
  • Packaging25g
  • Price$20.32
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002400
  • Product descriptionHypophosphorous acid 95
  • Packaging25g
  • Price$20.32
  • Updated2026-05-23
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberAN002400
  • Product descriptionHypophosphorous acid 95
  • Packaging10g
  • Price$17.78
  • Updated2026-05-23
  • Buy
  • ManufacturerGFS CHEMICALS
  • Product number45102
  • Product descriptionHypophosphorous acid 50%
  • Packaging2.5kg
  • Price$224.33
  • Updated2021-12-16
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  • ManufacturerGFS CHEMICALS
  • Product number45101
  • Product descriptionHYPOPHOSPHOROUS ACID SOLUTION, 50% AQUEOUS
  • Packaging500G
  • Price$109.14
  • Updated2026-06-03
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number1.04633
  • Product descriptionHypophosphorous acid 50% for analysis EMSURE?
  • Packaging500mL
  • Price$397
  • Updated2026-04-30
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  • ManufacturerSigma-Aldrich
  • Product number214906
  • Product descriptionHypophosphorous acid solution 50 wt. % in H2O
  • Packaging500g
  • Price$130
  • Updated2026-04-30
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number214906
  • Product descriptionHypophosphorous acid solution 50 wt. % in H2O
  • Packaging4kg
  • Price$688
  • Updated2026-04-30
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number214906
  • Product descriptionHypophosphorous acid solution 50 wt. % in H2O
  • Packaging4x4kg
  • Price$1690
  • Updated2026-04-30
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ING0004334 HYPOPHOSPHOROUS ACID 95.00% 50G $2460.42 2021-12-16 Buy
American Custom Chemicals Corporation ING0004334 HYPOPHOSPHOROUS ACID 95.00% 500G $4304.54 2021-12-16 Buy
Atlantic Research Chemicals AN002398 Hypophosphorous acid (50% w/w aq sol) 95 1g $10.16 2026-05-23 Buy
Atlantic Research Chemicals AN002400 Hypophosphorous acid 95 1g $10.16 2026-05-23 Buy
Atlantic Research Chemicals AN002398 Hypophosphorous acid (50% w/w aq sol) 95 5g $15.24 2026-05-23 Buy
Atlantic Research Chemicals AN002400 Hypophosphorous acid 95 5g $15.24 2026-05-23 Buy
Atlantic Research Chemicals AN002398 Hypophosphorous acid (50% w/w aq sol) 95 10g $17.78 2026-05-23 Buy
Atlantic Research Chemicals AN002398 Hypophosphorous acid (50% w/w aq sol) 95 25g $20.32 2026-05-23 Buy
Atlantic Research Chemicals AN002400 Hypophosphorous acid 95 25g $20.32 2026-05-23 Buy
Atlantic Research Chemicals AN002400 Hypophosphorous acid 95 10g $17.78 2026-05-23 Buy
GFS CHEMICALS 45102 Hypophosphorous acid 50% 2.5kg $224.33 2021-12-16 Buy
GFS CHEMICALS 45101 HYPOPHOSPHOROUS ACID SOLUTION, 50% AQUEOUS 500G $109.14 2026-06-03 Buy
Sigma-Aldrich 1.04633 Hypophosphorous acid 50% for analysis EMSURE? 500mL $397 2026-04-30 Buy
Sigma-Aldrich 214906 Hypophosphorous acid solution 50 wt. % in H2O 500g $130 2026-04-30 Buy
Sigma-Aldrich 214906 Hypophosphorous acid solution 50 wt. % in H2O 4kg $688 2026-04-30 Buy
Sigma-Aldrich 214906 Hypophosphorous acid solution 50 wt. % in H2O 4x4kg $1690 2026-04-30 Buy

Properties

Melting point :-25 °C
Boiling point :108 °C (759.8513 mmHg)
Density :1.206 g/mL at 20 °C(lit.)
vapor pressure :<17 mmHg ( 20 °C)
storage temp. :no restrictions.
solubility :very soluble in H2O, ethanol, ethyl ether
pka :pK1 1.1.
form :hygroscopic crystals or colorless oily liquid
color :Colorless
PH :pKa1= 1.00(25℃)
Water Solubility :SOLUBLE
Merck :13,4894
Stability :Stable. Incompatible with strong bases. Reacts violently with oxidizing agents, strong bases, mercury (II) nitrate and mercury (II) oxide. Do not heat above 100 C.
InChI :1S/H3O2P/c1-3-2/h3H2,(H,1,2)
InChIKey :GQZXNSPRSGFJLY-UHFFFAOYSA-N
SMILES :O[PH2]=O
CAS DataBase Reference :6303-21-5(CAS DataBase Reference)
NIST Chemistry Reference :Hypophosphorous acid(6303-21-5)
EPA Substance Registry System :Phosphinic acid (6303-21-5)

Safety Information

Symbol(GHS): Corrosion (GHS05)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to..…

Description

Hypophosphorous acid is primarily used for electroless nickel plating. It is involved in the reduction of arenediazonium salts. It acts as an additive in Fischer esterification reactions. Also, it serves as a neutralizing agent, antioxidant, catalyst in polymerization and poly condensation, and wetting agent. Further, it is used in the formulation of pharmaceuticals, discoloration of polymers, water treatment and retrieval of precious or non-ferrous metals. In addition to this, it is used as bleaching agents for plastics, synthetic fibers, decolorizing agent and for color stabilization during the manufacture of chemicals and several plastics.

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