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ChemicalBook >> CAS DataBase List >> Phenylmagnesium bromide

Phenylmagnesium bromide

Phenylmagnesium bromide price.
  • $18 - $7045.5
  • Product name: Phenylmagnesium bromide
  • CAS: 100-58-3
  • MF: C6H5BrMg
  • MW: 181.31
  • EINECS:202-867-2
  • MDL Number:MFCD00000038
  • Synonyms:PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN;Phenylmagnesiumbromide,3Minether;Magnesium, bromophenyl-;phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal;Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles;Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L);PHENYLMAGNESIUM BROMIDE, 3.0M SOLUTION I N DIETHYL ETHER;PHENYLMAGNESIUM BROMIDE SOLUTION, ~1 M I N THF
43 prices
Selected condition:
Brand
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Biosynth
  • Oakwood
  • Rieke Metals
  • Sigma-Aldrich
  • Strem Chemicals
  • Synthonix
  • TCI Chemical
  • Thermo Scientific Chemicals
  • TRC
  • Usbiological
Package
  • 10ml
  • 0.25mole
  • 25ml
  • 50mL
  • 1mole
  • 4X25ML
  • 100ML
  • 200ml
  • 250g
  • 500ML
  • 800ml
  • 1L
  • 18l
  • 25kg
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging100ML
  • Price$2483.25
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging500ML
  • Price$4504.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging1L
  • Price$7045.5
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR320048
  • Product descriptionPhenylmagnesium bromide 2M solution in 2-MeTHF
  • Packaging100ml
  • Price$108
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth
  • Product numberFP34331
  • Product descriptionPhenyl-magnesium bromide solution - 1.0 M in THF
  • Packaging25kg
  • Price$3245
  • Updated2026-06-04
  • Buy
  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging10ml
  • Price$18
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging25ml
  • Price$25
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging100ml
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number3218
  • Product descriptionPhenylmagnesium bromide
  • Packaging100mL
  • Price$167
  • Updated2026-05-06
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0440
  • Product descriptionPhenylmagnesium Bromide
  • Packaging50mL
  • Price$175
  • Updated2026-05-06
  • Buy
  • ManufacturerRieke Metals
  • Product numberT0440
  • Product descriptionPhenylmagnesium Bromide
  • Packaging100mL
  • Price$174
  • Updated2026-05-06
  • Buy
  • ManufacturerRieke Metals
  • Product numberT0440
  • Product descriptionPhenylmagnesium bromide
  • Packaging100mL
  • Price$152
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0440
  • Product descriptionPhenylmagnesium Bromide
  • Packaging100mL
  • Price$335
  • Updated2026-05-06
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0M in diethyl ether
  • Packaging100ml
  • Price$109
  • Updated2026-04-30
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0?M in diethyl ether
  • Packaging4X25ML
  • Price$104
  • Updated2026-04-30
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  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging4X25ML
  • Price$95.5
  • Updated2026-04-30
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 100ML $2483.25 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 500ML $4504.5 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 1L $7045.5 2021-12-16 Buy
Apolloscientific OR320048 Phenylmagnesium bromide 2M solution in 2-MeTHF 100ml $108 2021-12-16 Buy
Biosynth FP34331 Phenyl-magnesium bromide solution - 1.0 M in THF 25kg $3245 2026-06-04 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 10ml $18 2021-12-16 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 25ml $25 2021-12-16 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 100ml $75 2021-12-16 Buy
Rieke Metals 3218 Phenylmagnesium bromide 100mL $167 2026-05-06 Buy
Rieke Metals G0440 Phenylmagnesium Bromide 50mL $175 2026-05-06 Buy
Rieke Metals T0440 Phenylmagnesium Bromide 100mL $174 2026-05-06 Buy
Rieke Metals T0440 Phenylmagnesium bromide 100mL $152 2021-12-16 Buy
Rieke Metals G0440 Phenylmagnesium Bromide 100mL $335 2026-05-06 Buy
Sigma-Aldrich 171565 Phenylmagnesium bromide solution 3.0M in diethyl ether 100ml $109 2026-04-30 Buy
Sigma-Aldrich 171565 Phenylmagnesium bromide solution 3.0?M in diethyl ether 4X25ML $104 2026-04-30 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0?M in THF 4X25ML $95.5 2026-04-30 Buy

Properties

Melting point :153-154 °C
Density :1.134 g/mL at 25 °C
Flash point :−40 °F
storage temp. :water-free area
solubility :Miscible with tetrahydrofuran.
form :Liquid
color :Yellow to brown
Specific Gravity :1.14
Appearance :Clear to slightly hazy colorless to dark brown liquid.
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :3588849
InChI :InChI=1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChIKey :ANRQGKOBLBYXFM-UHFFFAOYSA-M
SMILES :C1([Mg]Br)C=CC=CC=1
CAS DataBase Reference :100-58-3(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, bromophenyl- (100-58-3)

Safety Information

Symbol(GHS): Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

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