(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE synthesis
- Product Name:(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
- CAS Number:14212-54-5
- Molecular formula:C9H10O
- Molecular Weight:134.18
873-66-5
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$35.00/250 mg
100-52-7
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$17.30/2g
4518-66-5
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$142.00/1g
14212-54-5
15 suppliers
$163.00/1g
Yield: 6% ， 86% ， 8%
Reaction Conditions:
with oxygen;isobutyraldehyde in acetonitrile at 45; for 8 h;enantioselective reaction;Reagent/catalyst;
Steps:
2.8. Catalytic aerobic oxidation of hydrocarbons
General procedure: The oxidation of hydrocarbons was performed in a 25-mL round-bottom flask equipped with a condenser in a thermostated oil bath at 45 °C. In a typical experiment the flask was charged with the suspension of catalyst SBA15-[MnIII(TCPP-R*)Cl] (10.0 mg; contains 63.7 lmol Mn), 5 mL acetonitrile, 0.10 g chlorobenzene as internal standard, substrate and 5 mmol isobutyraldehyde. Dioxygen was provided using an oxygen balloon. The reaction mixture was stirred at 45 °C for 8 h. At appropriate intervals, aliquots were removed and analyzed by GC-FID. The products were identified with authentic samples and 1H-NMR spectroscopy.
References:
Farokhi, Afsaneh;Hosseini Monfared, Hassan [Journal of Catalysis,2017,vol. 352,p. 229 - 238]
637-50-3
114 suppliers
$47.00/1 g
14212-54-5
15 suppliers
$163.00/1g
873-66-5
126 suppliers
$35.00/250 mg
4518-66-5
12 suppliers
$142.00/1g
14212-54-5
15 suppliers
$163.00/1g
873-66-5
126 suppliers
$35.00/250 mg
14212-54-5
15 suppliers
$163.00/1g
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
1000210-73-0
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14212-54-5
15 suppliers
$163.00/1g