2,7-Dichlorofluorene synthesis
- Product Name:2,7-Dichlorofluorene
- CAS Number:7012-16-0
- Molecular formula:C13H8Cl2
- Molecular Weight:235.11
86-73-7
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7012-16-0
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$7.00/1g
Yield:7012-16-0 40.9%
Reaction Conditions:
with chlorine;acetic acid at 40; for 2 h;
Steps:
1 Example 1: Fluorene chloride
1200 mL of glacial acetic acid, 166.2 g (1 mol) of hydrazine (I) and a 2500 mL four-necked flask were maintained to maintain an internal temperature of 40 ° C.The chlorine gas was introduced under the right mechanical stirring, and the reaction was detected by high performance liquid chromatography until the basic reaction of 2-chloroindole was completed. Stop chlorine,Stir at 40 ° C for 2 h, warm to reflux until the reaction solution is completely soluble, cool to room temperature, filtered, solid 2,7-dichloropurine, after drying98 g, liquid phase content of 98.2% (0.409 mol), yield 40.9%. The mother liquor is a yellow transparent liquid, which is detected by liquid chromatography.The contents of the relevant components are shown in Table 1.
References:
Shaoxing University;Zhejiang Lai Yi Biological Co., Ltd.;Shen Runpu;Chen Weizhong;Shi Jiuhao;Liu Jian;Chang Kaikai;Qiu Jiangying;Shen Caiyun;Sheng Guodong;Feng Chengjie CN108586189, 2018, A Location in patent:Paragraph 0022-0025
6297-11-6
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7012-16-0
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19099-48-0
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7012-16-0
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58775-07-8
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7012-16-0
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58775-15-8
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7012-16-0
257 suppliers
$7.00/1g