2,7-DIIODOFLUORENE synthesis
- Product Name:2,7-DIIODOFLUORENE
- CAS Number:16218-28-3
- Molecular formula:C13H8I2
- Molecular Weight:418.01
86-73-7
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64-17-5
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$10.00/50g
16218-28-3
106 suppliers
$13.00/250mg
Yield:-
Reaction Conditions:
with Iodine monochloride
Steps:
IV EXAMPLE IV
EXAMPLE IV Iodine monochloride (10 g) was dissolved in 30 ml of TMP with cooling. Considerable heat evolved. This solution was added dropwise to a solution of 5 g of fluorene in 30 ml TMP stirred, held at 83°-100° C overnight (about 12 hours), refrigerated (at 5° C for about 6 hours) and filtered to give 4.8 g of white, fine needles. Another 2.4 g was recovered from filtrate - total crude yield 60%. Recrystallized from tetrahydrofuran to which a few (2) ml of ethyl alcohol was added 2,7-Diiodofluorene was obtained: 5.6 g, 44% of white needles, mp 214°-215°, reported (in F. Dewhurst, P. K. J. Shah, J. Chem. Soc., 1503 (1969)) mp 214° C.
References:
Pearson;Donald E. US3988369, 1976, A
86-73-7
409 suppliers
$6.00/25g
16218-28-3
106 suppliers
$13.00/250mg
86-73-7
409 suppliers
$6.00/25g
16218-28-3
106 suppliers
$13.00/250mg
2523-42-4
195 suppliers
$6.00/250mg
2523-42-4
195 suppliers
$6.00/250mg
16218-28-3
106 suppliers
$13.00/250mg
525-64-4
195 suppliers
$24.19/250mg
16218-28-3
106 suppliers
$13.00/250mg