2-ETHYLADAMANTANE synthesis
- Product Name:2-ETHYLADAMANTANE
- CAS Number:14451-87-7
- Molecular formula:C12H20
- Molecular Weight:164.29
14648-57-8
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14451-87-7
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$496.23/5MG
Yield:14451-87-7 89%
Reaction Conditions:
with trifluoroacetic acid in hexane at 25 - 50; for 51 h;
Steps:
2-Methyladamantane (9)
General procedure: 2-Methyladamantan-2-ol, 30 g (0.18 mol), was dissolved in 40 mL of trifluoroacetic acid, and a mixture of 30 mL of GKZh-94 organosilicon oligomer and 40 mL of hexane was added dropwise at a temperature not exceeding 25°C. The mixture was stirred for 1 h and kept at 45-50°C for 50 h. The mixture was cooled, neutralized with 120 mL of a 20% solution of sodium hydroxide, refluxed for 5 h, and steam-distilled. The distillate was extracted with pentane, and the extract was passed through a silica gel column and evaporated. Yield 25 g (92%), mp 151-153°C (from acetone) [68].
References:
Ivleva, E. A.;Klimochkin, Yu. N.;Leonova, M. V. [Russian Journal of Organic Chemistry,2020,vol. 56,# 10,p. 1702 - 1710][Zh. Org. Khim.,2020,vol. 56,# 10,p. 1516 - 1526,11]
![Tricyclo[3.3.1.13,7]decane, 2-butyl-](/CAS/20210111/GIF/14449-43-5.gif)
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14451-87-7
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![Tricyclo[3.3.1.13,7]decane, 2-propyl-](/CAS/20210111/GIF/14451-88-8.gif)
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