4-(HYDROXYMETHYL)CYCLOHEXANONE synthesis
- Product Name:4-(HYDROXYMETHYL)CYCLOHEXANONE
- CAS Number:38580-68-6
- Molecular formula:C7H12O2
- Molecular Weight:128.17
10596-05-1
33893-85-5
1653-30-1
38580-68-6
Example 5: Ce(IV)/PFCP (50 mg, 0.027 mmol) and NaBrO3 (200 mg) were dispersed and dissolved in acetic acid. Subsequently, 1,10-undecanediol (1.0 mmol) and 4-hydroxymethylcyclohexanol (1.0 mmol) were added, respectively. The reaction mixture was heated at 55°C for 3 hours. Upon completion of the reaction, the products were purified by column chromatography to afford 10-undecan-1-ol (154 mg, 82% yield) and 4-hydroxymethylcyclohexanone (93 mg, 73% yield).
10596-05-1
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33893-85-5
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1653-30-1
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38580-68-6
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Yield:38580-68-6 73%
Reaction Conditions:
with NaBrO3;acetic acid in Ce
Steps:
5 EXAMPLE 5
EXAMPLE 5 To acetic acid in which Ce (IV)/PFCP (50 mg, 0.027 mmole) and 200 mg of NaBrO3 were dispersed and dissolved, 1.0 mmole of 1,10-undecane diol and 1.0 mmole of 4-hydroxymethyl cyclohexanol were added, respectively. The reaction mixture was heated for three hours at 55° C. and the product was purified with a column chromatography to yield 154 mg (82% yield) of 10-undecane-1-ol and 93 mg (73% yield) of 4-hydroxymethyl cyclohexanone.
References:
E. I. Du Pont de Nemours and Company US4617153, 1986, A
17159-79-4
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38580-68-6
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33893-85-5
75 suppliers
$24.00/100mg
38580-68-6
137 suppliers
$80.29/0.5g
![ethyl 1,4-dioxaspiro[4.5]decane-8-carboxylate](/CAS/GIF/1489-97-0.gif)
1489-97-0
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38580-68-6
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94458-92-1
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38580-68-6
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