5-BROMO-2-THIENYLZINC BROMIDE synthesis
- Product Name:5-BROMO-2-THIENYLZINC BROMIDE
- CAS Number:151073-94-8
- Molecular formula:C4H2Br2SZn
- Molecular Weight:307.32
3141-27-3
317 suppliers
$5.00/10g
151073-94-8
16 suppliers
$156.00/50ml
Yield:-
Reaction Conditions:
with zinc at 20; for 1 h;
Steps:
Preparation of 3-bromo-2-methylthiophen-5-ylzinc bromide (II)
General procedure: In an oven-dried 250mL round-bottomed flask equipped with a stir bar was added 4.70 g of active zinc (Zn, 72.0 mmol). 3,5-Dibromo-2-methylthiophene (15.36 g, 60.0mmol) was cannulated neat into the flask at room temperature. The resulting mixture was stirred for 1.0 h at room temperature. The whole mixture was settled down and then the supernatant was used for the subsequent coupling reactions.
References:
Cheon, Jong-Woo;Cho, Hyun-Hee;Kim, Seung-Hoi [Bulletin of the Korean Chemical Society,2015,vol. 36,# 4,p. 1266 - 1269]
3141-27-3
317 suppliers
$5.00/10g
7440-66-6
0 suppliers
$14.00/5g
151073-94-8
16 suppliers
$156.00/50ml