CYCLOHEXANE-1 4-DICARBONITRILE 98% MIXT& synthesis
- Product Name:CYCLOHEXANE-1 4-DICARBONITRILE 98% MIXT&
- CAS Number:10534-13-1
- Molecular formula:C8H10N2
- Molecular Weight:134.18
105-08-8
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10534-13-1
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$45.39/1g
Yield: 80.5%
Reaction Conditions:
with 1,10-Phenanthroline;ammonia;oxygen in 1,4-dioxane at 30 - 60; under 3750.38 Torr; for 12 h;Pressure;Temperature;Reagent/catalyst;Solvent;
Steps:
1-7 Example 2
0.1 mmol α-MnO 2 catalyst with 0.01 mmolPhenanthrolineInto a 20 mL lined reactor,Add 10 mL of dioxane and stir at 30 ° C for 72 h.Then add 1 mmol of 1,4-cyclohexanedimethanol.Filled with 0.5MPa NH3 and 0.5MPa oxygen,After heating to 60 ° C for 12 h, cool down.Qualitative analysis of the obtained samples by gas chromatography-mass spectrometryTechnology, quantitative analysis is achieved by gas chromatography.The conversion of 1,4-cyclohexanedimethanol was 91.2%.1,4-cyclohexane dicarbonitrileThe selectivity was 96.3%.The isolated yield of 1,4-cyclohexane dicarbonitrile is 80.5%.The purity of the gas chromatograph was 99.0%.
References:
Dalian Institute of Chemical Physics;Xu Jie;Jia Xiuquan;Ma Jiping;Li Xiaofang;Gao Jin;Xu Yongming;Xia Fei CN109956887, 2019, A Location in patent:Paragraph 0021-0034
20101-86-4
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10534-13-1
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4848-16-2
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10534-13-1
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2549-93-1
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10534-13-1
23 suppliers
$45.39/1g