DECYL-PYRIDIN-2-YL-AMINE synthesis
- Product Name:DECYL-PYRIDIN-2-YL-AMINE
- CAS Number:101259-87-4
- Molecular formula:C15H26N2
- Molecular Weight:234.38
Yield:101259-87-4 92%
Reaction Conditions:
with trifuran-2-yl-phosphane;palladacycle;lithium hydroxide in neat (no solvent) at 120; for 24 h;Molecular sieve;Inert atmosphere;
Steps:
2.3. General procedure for N-alkylation of amines using primary and secondary alcohols
General procedure: A similar protocol as mentioned for N-alkylation of amines using benzyl alcohol was used. The quantities involved are as follows: Amine (3.0 mmol), alcohol (6.0 mmol), LiOH (1.5 mmol), precatalyst (1.5*10-2 mmol, 0.50 mol %), P(2-Fur)3 (1.5*10-2 mmol, 1.00 mol%) and activated 4 ? MS (100 mg). The reaction mixture was stirred at 120-130 °C for 24-48 h.
References:
Mamidala, Ramesh;Mukundam, Vanga;Dhanunjayarao, Kunchala;Venkatasubbaiah, Krishnan [Tetrahedron,2017,vol. 73,# 16,p. 2225 - 2233] Location in patent:supporting information
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