Malonamide synthesis
- Product Name:Malonamide
- CAS Number:108-13-4
- Molecular formula:C3H6N2O2
- Molecular Weight:102.09
A typical reaction was carried out in a 10 mL flask. Benzonitrile (2 mmol), CuII-4 ? (0.2 g), acetaldoxime (6 mmol) and MeOH (4 mL) were stirred at 65 °C for 4 h. The solid was filtered, washed with MeOH and the filtrate evaporated. The residue was subjected to GC-MS analysis and NMR spectroscopy. The filtered catalyst can be recycled after drying at about 150 °C for 1 h.
109-77-3
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$10.00/5g
108-13-4
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$9.00/1g
Yield:108-13-4 98%
Reaction Conditions:
with Acetaldehyde oxime in methanol at 65; for 4 h;
Steps:
General procedure: A typical reaction was carried out in a 10 mL flask. Benzonitrile (2 mmol), CuII-4 ? (0.2 g), acetaldoxime (6 mmol) and MeOH (4 mL) were stirred at 65 °C for 4 h. The solid was filtered, washed with MeOH and the filtrate evaporated. The residue was subjected to GC-MS analysis and NMR spectroscopy. The filtered catalyst can be recycled after drying at about 150 °C for 1 h.
References:
Kiss, árpád;Hell, Zoltán [Tetrahedron Letters,2011,vol. 52,# 45,p. 6021 - 6023] Location in patent:experimental part
107-91-5
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108-13-4
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$9.00/1g
67-56-1
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598-42-5
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$61.00/1g
108-13-4
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598-41-4
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141-82-2
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108-13-4
287 suppliers
$9.00/1g
105-53-3
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108-13-4
287 suppliers
$9.00/1g