METHYL FLUOROSULFONATE synthesis
- Product Name:METHYL FLUOROSULFONATE
- CAS Number:421-20-5
- Molecular formula:CH3FO3S
- Molecular Weight:114.1
812-01-1
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$168.00/250 mg
421-20-5
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$45.00/100mg
Yield: 75.9%
Reaction Conditions:
with bis(2,2,2-trifluoroethyl) sulfate;hydrogen fluoride at 80; for 8 h;
Steps:
7 A method for preparing methyl fluorosulfonate comprises the following steps:
Add 261.0 g of methyl chlorosulfonate to a 500 mL PTFE reactor.Turn on the agitation. 10 g of bistrifluoroethanol sulfate was added and the temperature was raised to 80 ° C.Approximately 40g of anhydrous hydrogen fluoride gas is introduced at a constant rate.Maintain the reaction temperature at 80 ± 5 ° C,The reaction was stopped for 8 hours, the reaction was stopped, and hydrogen fluoride was removed by nitrogen.Atmospheric distillation, collecting fractions at 92-93 ° C173.4g,Purity 99.1%,The yield was 75.9%.
References:
Shanghai Rukun New Materials Co., Ltd.;Shen Fengfeng;Liu Jicheng CN109734633, 2019, A Location in patent:Paragraph 0097; 0098; 0099; 0100
77-78-1
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$19.69/1ml
421-20-5
61 suppliers
$45.00/100mg
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
74-88-4
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$15.00/10g
421-20-5
61 suppliers
$45.00/100mg
616-42-2
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$12.00/5g
421-20-5
61 suppliers
$45.00/100mg